Neodymium nitrate

Inorganic chemical compound From Wikipedia, the free encyclopedia

Neodymium nitrate is an inorganic salt with the formula Nd(NO3)3·x(H2O). It is typically encountered as the hexahydrate, Nd(NO3)3·6H2O. It decomposes to NdONO3 at elevated temperature.[5]

Quick facts Names, Identifiers ...
Neodymium(III) nitrate
Names
Other names
Neodymium trinitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.127 Edit this at Wikidata
EC Number
  • 233-153-9
  • hexahydrate: InChI=1S/3NO3.Nd.6H2O/c3*2-1(3)4;;;;;;;/h;;;;6*1H2/q3*-1;+3;;;;;;
    Key: VQVDTKCSDUNYBO-UHFFFAOYSA-N
  • [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Nd+3]
  • hexahydrate: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.[Nd+3]
Properties
  • Nd(NO3)3 (anhydrous)
  • Nd(NO3)3·6H2O (hexahydrate)
Molar mass
  • 330.25 gmol−1 (anhydrous)
  • 438.34 gmol−1 (hexahydrate)
Appearance vibrant pink/violet solid
Density 6.5 g/cm3
Melting point 55 °C (131 °F; 328 K)[1] (hexahydrate, melts in water of crystallization)
Structure[2]
triclinic
P1
a = 9.307 Å, b = 11.747 Å, c = 6.776 Å
α = 91.11°, β = 112.24°, γ = 109.15°
Values are for [Nd(NO3)3(H2O)4]·2H2O.
639.0 Å3
2
Hazards
GHS labelling:[3]
GHS03: OxidizingGHS07: Exclamation mark
Warning
H272, H315, H319, H335
P210, P220, P221, P261, P264, P271, P280, P302+P352, P304+P340+P312, P305+P351+P338, P332+P313, P337+P313, P362, P370+P378, P403+P233, P405, P501
NFPA 704 (fire diamond)
Lethal dose or concentration (LD, LC):
2750 mg/kg (oral, rat)[4]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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It is used in the extraction and purification of neodymium from its ores.[6]

Production and Preparation

Neodymium(III) nitrate can be obtained by the action of nitric acid on neodymium(III) carbonate or other neodymium salts of weak acids.

References

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