Neptunium(VII) oxide-hydroxide

From Wikipedia, the free encyclopedia

Neptunium(VII) oxide-hydroxide
Names
Other names
Neptunyl hydroxide
Identifiers
3D model (JSmol)
  • InChI=1S/Np.3H2O.2O/h;3*1H2;;/q+3;;;;;/p-3
    Key: QJJOKRDJFDRNCY-UHFFFAOYSA-K
  • [Np+3](=O)=O.[OH-].[OH-].[OH-]
Properties
NpO2(OH)3
Molar mass 320.02 g/mol
Appearance Black solid
10 mg/l
Solubility Soluble in nitric acid and 1 M potassium hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Neptunium(VII) oxide-hydroxide is a chemical compound which has neptunium in its highest oxidation state of +7. This compound reacts with basic salts such as potassium hydroxide to form neptunates (NpO53-) and water.[1]

NpO2(OH)3 + 3KOH → K3NpO5 + 3H2O

Neptunium(VII) oxide-hydroxide is stable in an alkaline solution, however, it is slowly reduced to Np(VI) in an acidic solution. In water, it forms a greenish solution.[1] This compound decomposes slowly to an oxidized solid.[2]

References

Related Articles

Wikiwand AI