Neptunium trioxide

Chemical compound From Wikipedia, the free encyclopedia

Neptunium trioxide is an inorganic compound of neptunium and oxygen with the chemical formula NpO3.[1]

Quick facts Names, Identifiers ...
Neptunium trioxide
Names
Other names
Neptunium(VI) oxide
Identifiers
Properties
NpO3
Molar mass 285 g·mol−1
Appearance dark brown crystals (hydrate)
insoluble
Related compounds
Other cations
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis

Neptunium trioxide can be obtained by oxidating neptunium(V) nitrate solution in a molten eutectic mixture of potassium and lithium nitrates with ozone at 150 °C. The reaction by-products are washed out with water.[2] Other methods are also known.[3][4]

Physical properties

Neptunium trioxide is highly volatile and exists only in the hydrated form. It is insoluble in water. It forms dark brown hydrate crystals of variable composition NpO3•xH2O, where x = 1–2.[5] The NpO3•H2O hydrate crystals are of orthorhombic system.

References

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