Oxotrichlorobis(triphenylphosphine)rhenium(V)

Oxotrichlorobis(triphenylphosphine)rhenium(V)
Names
	IUPAC name Trichloridooxidobis(triphenylphosphane)rhenium(V)
Identifiers
CAS Number	17442-18-1 ;
3D model (JSmol)	Interactive image; Interactive image;
ChemSpider	19374409;
PubChem CID	25210853;
	InChI InChI=1S/2C18H15P.3ClH.O.Re/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;;/h21-15H;3*1H;;/q;;;;;-2;+5/p-3 Key: QYKOBCZMNRLXRH-UHFFFAOYSA-K;
	SMILES Cl[Re-2](Cl)(Cl)(=O)([P+](c1ccccc1)(c1ccccc1)c1ccccc1)[P+](c2ccccc2)(c2ccccc2)c2ccccc2; C1(P(C2=CC=CC=C2)C3=CC=CC=C3)=CC=CC=C1.C4(P(C5=CC=CC=C5)C6=CC=CC=C6)=CC=CC=C4.[O-2].[Cl-].[Cl-].[Cl-].[Re+5];
Properties
Chemical formula	ReOCl3(PPh3)2
Molar mass	833.15 g/mol
Appearance	yellow microcrystals
Melting point	205 °C (401 °F; 478 K)
Solubility in water	not soluble in water
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Oxotrichlorobis(triphenylphosphine)rhenium(V) is the chemical compound with the formula Re O Cl₃(P Ph₃)₂. This yellow, air-stable solid is a precursor to a variety of other rhenium complexes.^[1] In this diamagnetic compound, Re has an octahedral coordination environment with one oxo, three chloro and two mutually trans triphenylphosphine ligands. The oxidation state of rhenium is +5 and its configuration is d².

[1]

Oxotrichlorobis(triphenylphosphine)rhenium(V)

Uses

References

Related Articles