Partial melting

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Partial melting is the phenomenon that occurs when a rock is subjected to temperatures high enough to cause certain minerals to melt, but not all of them. Partial melting is an important part of the formation of all igneous rocks and some metamorphic rocks (e.g., migmatites), as evidenced by a multitude of geochemical, geophysical and petrological studies.[1]

The parameters that influence partial melting include the composition of the source rock, the pressure and temperature of the environment, and the availability of water or other fluids.[2][1] As for the mechanisms that govern partial melting, the main are decompression melting and flux melting. Decompression melting occurs when rocks are brought from higher to lower pressure zones in the Earth's crust, lowering the melting point of its mineral components, thus generating a partial melt. Flux melting, on the other hand, occurs when water and other volatiles get in contact with hot rock, reducing the melting point of minerals, leading to partial melting.[2] With a few exceptions (e.g., Yellowstone[3]), conduction of heat is considered a mechanism too slow and inefficient to partially melt large bodies of rock.[2]

Partial melting is also linked to the formation of ores. Magmatic and hydrothermal ore deposits, such as chromite, Ni-Cu sulfides, rare-metal pegmatites, kimberlites, volcanic-hosted massive sulfide deposits are some examples of valuable natural resources closely related to the conditions of the origin, migration and emplacement of partial melts.[4]

Composition

A rock with composition CB starts to melt when its temperature is TA and reaches the solidus curve, the temperature below which all the substance is solid. The newly formed liquid phase has an initial composition of CL at TA. As the temperature increases towards TB, the partial melting of the solid phase leads to changes in composition from CB to CS (blue line). As the liquid phase increases, its composition gets closer to the rock’s original composition CB (red line). When the temperature reaches TB, the whole solid phase has melted, characterizing the substance being above the liquidus curve.[5][6]

Melting in the mantle depends on the following parameters: composition of the rocks, pressure and temperature, and the presence of volatiles.

The chemical composition of rocks affects their melting points and the final product of partial melting. For example, the bulk chemistry of melts obtained experimentally from sedimentary rocks, such as shales and graywacke reflects that of the source rocks.[7] Additionally, rocks containing minerals with lower melting points will undergo partial melting more easily under the same conditions of pressure and temperature if compared to minerals with higher melting points.[4]

Temperature and pressure

Temperature and pressure can have a significant impact on the amount of partial melting that occurs in rocks. When temperature is low, the pressure needs to be low as well for melting to occur, and when temperature is high, the pressure needs to be higher to prevent melting from taking place. Higher pressure can suppress melting, while higher temperature can promote it. The extent to which partial melting occurs depends on the balance between temperature and pressure, with both having a strong influence on the process.[5]

Addition of volatiles

The presence of volatiles has the potential to significantly reduce solidus temperatures of a given system.[8][9] This allows for melt to be generated at lower temperatures than otherwise predicted, eliminating the need for a change in pressure or temperature conditions of the system. Furthermore, some consider that volatiles control the stability of minerals and the chemical reactions that happen during partial melting,[10] while others assign a more subordinate role to these components.[11]

Mechanisms

Significance

References

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