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Plutonium(IV) iodate

Chemical compound From Wikipedia, the free encyclopedia

Plutonium(IV) iodate is an inorganic compound with the chemical formula Pu(IO3)4, it is a salt which decomposes into plutonium(IV) oxide above 540 °C.[3] It can be generated in the reaction of plutonium(IV) nitrate and iodic acid, but this method cannot obtain a pure product;[3] Another preparation method is the reaction of plutonium(IV) nitrate or plutonium(IV) chloride with potassium iodate and dilute nitric acid.[4] It can crystallize in the tetragonal crystal system with space group P42/n.[2]

Quick facts Names, Identifiers ...
Plutonium(IV) iodate
Names
Other names
Plutonium tetraiodate
Identifiers
3D model (JSmol)
  • InChI=1S/Pu.4HIO3/c;4*2-1(3)4/h;4*(H,2,3,4)/q+4;;;;/p-4
    Key: KZCPVUXVUIMYAF-UHFFFAOYSA-J
  • [O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[Pu+4]
Properties
Pu(IO3)4
Molar mass 943.61
Appearance Green to brown transition depending on crystal angle[1]
Density 6.074 g·cm−3(−80 °C)[2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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