Plutonium oxyfluoride

Chemical compound From Wikipedia, the free encyclopedia

Plutonium oxyfluoride is an inorganic compound of plutonium, oxygen, and fluorine with the chemical formula PuOF.[1][2]

Quick facts Names, Identifiers ...
Plutonium oxyfluoride
Names
Other names
Plutonium oxide fluoride
Identifiers
3D model (JSmol)
  • InChI=1S/FH.O.Pu/h1H;;/q;-2;+3/p-1
    Key: MBMNUTPHGDIIRF-UHFFFAOYSA-M
  • [F-].[O-2].[Pu+3]
Properties
PuOF
Molar mass 279 g/mol
Appearance metallic crystals
Density 9.76 g/cm3
insoluble
Structure
Cubic
Related compounds
Related compounds
Lanthanum oxyfluoride Neodymium oxyfluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis

Plutonium oxyfluoride may be produced by the reduction of plutonium(IV) fluoride with oxygen admixture:[3]

2PuF4 + 3H2 + O2 → 2PuOF + 6HF

Physical properties

PuOF forms gray crystals of the cubic crystal system[4] with metallic luster, cell parameters a = 0.571 nm, Z = 4, structure type CaF2.

Plutonium oxyfluoride does not dissolve in water.

References

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