Plutonium tetroxide

Compound of plutonium and oxygen From Wikipedia, the free encyclopedia

Plutonium tetraoxide is an inorganic binary compound of plutonium and oxygen with the chemical formula PuO4.[1] This is an exotic, higher-order oxide of plutonium where the metal is in the rare +8 oxidation state.[2][3] The compound is volatile and very hard to isolate.[4][5]

Quick facts Names, Identifiers ...
Plutonium tetraoxide
Names
Other names
Plutonium(VIII) oxide
Identifiers
3D model (JSmol)
  • InChI=1S/O2.2O.Pu/c1-2;;;/q-1;;;+1
    Key: KOOAIBAKTCSZCC-UHFFFAOYSA-N
  • O=[Pu+]=O.O=[O-]
Properties
PuO4
Molar mass 308 g·mol−1
insoluble (hydrates)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Theoretical calculations show that the molecule has the structure (O=Pu=O)+(O2)-.[2][contradictory]

References

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