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Praseodymium monophosphide

Chemical compound From Wikipedia, the free encyclopedia

Praseodymium monophosphide is an inorganic compound of praseodymium and phosphorus with the chemical formula PrP.[2][3][4] The compound forms crystals.

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Praseodymium monophosphide
Names
Other names
Phosphanylidynepraseodymium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.868 Edit this at Wikidata
EC Number
  • 235-068-2
  • InChI=1S/P.Pr
    Key: ZWIUVBLJANXBMO-UHFFFAOYSA-N
  • P#[Pr]
Properties
PPr
Molar mass 171.88142 g·mol−1
Appearance Dark green crystals[1]
Decomposes in water
Structure
cubic
Related compounds
Other anions
Praseodymium nitride
Praseodymium arsenide
Praseodymium antimonide
Praseodymium bismuthide
Other cations
Cerium phosphide
Neodymium phosphide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis

Praseoymium monophosphide can be prepared by heating praseodymium and phosphorus in the presence of iodine vapor:[5]

4 Pr + P4 → 4 PrP

Physical properties

Praseodymium monophosphide forms crystals of a cubic system, space group Fm3m, with cell parameters a = 0.5872 nm, Z = 4, and structure like sodium chloride NaCl.[6][7] It melts congruently at 3120 °C.

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