Preservation of magnetic audiotape

The first magnetic tapes were manufactured by BASF in Germany in 1932. They were designed with iron carbonyl as the magnetic pigment mixed into the cellulose acetate carrier. Production soon moved to iron oxide coated onto cellulose acetate rolls, cut into uniform strips, and wound onto plastic or metal hubs. Recordists began recording sound on magnetic media in the twenties in the form of magnetic wire. After World War II, the advantages of tape in terms of sturdiness and the ability to edit by cutting and splicing made tape preferable to wire as the magnetic medium of choice. Tape consists of a coating of a magnetic pigment, typically iron oxide (Fe₂O₃), on a long strip of polyester (polyethelyne terephthalate) base film. This base film has been used since the mid-sixties as a replacement for acetate bases film that was prone to chemical instability.

A new problem with chemical stability became notable in the mid-seventies when two significant tape manufacturers changed their dispersion formulations by introducing a polyurethane binder that, in time, turned hygroscopic and broke down as it absorbed water molecules into the long hydrocarbon molecular chains. The tape coatings became sticky and shed oxide onto all tape recorder parts in their path, including heads, guides, rollers, and capstans. This is commonly called sticky-shed syndrome. Although the problem was confined to two of the four major tape manufacturers (neither BASF nor 3M studio tapes suffer from the problem because neither manufacturer used the hygroscopic binder), the reputation of all magnetic tapes has been tainted by the defect.^{[citation needed]}

Information can be recovered from the "sticky-shed" tapes by heating them at a very low temperature in order to drive the water out of the binders.^[1] The baking method is a one-time solution to the problem because the binder remains unstable. Tapes that do not show the breakdown syndrome do not need any special treatment.^{[citation needed]}

It is advised that open reels are handled by the center hub area or by the outer edges of the reel flanges, if necessary, and that the actual tape is not touched. If the outer flanges must be used, do not squeeze the edges of the reel flanges together, as it will damage the edges of the tape. If possible, handle by the center hub only.^[2] Similarly, it is recommended that cassettes be handled by the existing outer plastic case and that fingers not be placed anywhere inside the cassette mechanism.^[3]

Magnetic tape must be kept clean in order to prevent scratching and deterioration. Dust on the surface of the tape will cause friction between the tape and the tape heads on the playback equipment, which will scratch the oxide layer. The website for sound preservation hosted by the National Library of Canada classifies dirt in two classes: Foreign matter (fingerprints, dust) and alteration of the original state (chemical reactions caused by grime and dirt deposited on the tape surface).^[2] In any event, the tapes must be properly cleaned.^{[citation needed]}

Recommended methods for removing dust on tapes include using a small vacuum with a hose or wiping with 3M Tape Cleaning Fabric. Care must be used when using a vacuum if a hose attachment is available. If the motor of the vacuum is powerful enough, it can demagnetize the tape, and the recording will be compromised. Many of the professional companies for tape restoration recommend professional help for proper care. They are generally correct to recommend this, as it is a delicate process that requires training if one plans to undertake serious chemical or physical repair. Vidipax, a professional tape restoration company, recommends using Pellon fabric or cloth as the safest and most efficient way to clean tapes. They warn against using solvents at all costs unless the tapes have already been submerged in water or another solvent (in the case of a flood). They also remind tape owners or collections managers that baking tapes to reverse hydrolysis is rarely a permanent fix and permanently alters the make-up of the tape.^[4]