R-454B

Refrigerant From Wikipedia, the free encyclopedia

R-454B, also known by the trademarked names Opteon XL41, Solstice 454B, and Puron Advance, is a zeotropic blend of 68.9 percent difluoromethane (R-32), a hydrofluorocarbon, and 31.1 percent 2,3,3,3-tetrafluoropropene (R-1234yf), a hydrofluoroolefin.[1] Because of its reduced global warming potential (GWP), R-454B is intended to be an alternative to refrigerant R-410A in new equipment.[2][3][4] R-454B has a GWP of 466, which is 78 percent lower than R-410A's GWP of 2088.[2]

R-454B is non-toxic and mildly flammable, with an ASHRAE safety classification of A2L. In the United States, it is expected to be packaged in a container that is red or has a red band on the shoulder or top. These containers are supplied with a left-hand thread valve to prevent cross-contamination.[2][5][6]

There is a shortage of R-454B in the United States as of May 2025.[7][8][9]

History

The refrigeration industry has been seeking replacements for R-410A because of its high global warming potential. R-454B, formerly known as DL-5A, has been selected by several manufacturers.[4][10][11][12][13]

R-454B was developed at and is manufactured by Chemours. Carrier first announced introduction of R-454B in ducted residential and light commercial packaged refrigeration and air conditioning products in 2018, with R-454B-based products launches starting in 2023.[14]

Physical & Thermodynamic Properties

More information Property, Typical Value ...
Property Typical Value
Molecular weight 62.6 g/mol
Normal boiling point (1 atm) −50.5 °C (−58.9 °F)
Critical temperature 78.1 °C (172.6 °F)
Critical pressure ≈ 52.7 bar (≈ 763.9 psia)
Critical density ≈ 443 kg/m³ (≈ 27.7 lb/ft³)
Temperature glide ≈ 1.5–2.3 °F (small, near-azeotropic behavior)
Liquid density (at 25 °C) ≈ 985–996.5 kg/m³
Vapor pressure (at 25 °C) ≈ 15.2–15.7 bar (≈ 1,516 kPa)
Heat of vaporization (at boiling point) ≈ 52.7 BTU/lb (or ≈ 316 kJ/kg)
Appearance Colorless
Lubricant compatibility Polyolester (POE) oil
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Operating pressures are generally similar to (or slightly lower than) R-410A, which allows relatively straightforward adaptation of existing equipment designs. Capacity and efficiency are typically close to or slightly better than R-410A in properly designed systems.

R-454B is not the only blend of R-32 and R-1234yf to be proposed as a refrigerant. Other blends include R-454A (35 percent R-32, 65 percent R-1234yf) and R-454C (21.5 percent R-32, 78.5 percent R1234yf). There are also several blends that include a third component.[1]

See also

References

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