Rhodium(III) nitrate

Chemical compound From Wikipedia, the free encyclopedia

Rhodium(III) nitrate is an inorganic compound, a salt of rhodium and nitric acid with the formula Rh(NO3)3. This anhydrous complex has been the subject of theoretical analysis but has not been isolated.[4] However, a dihydrate and an aqueous solution are known with similar stoichiometry; they contain various hexacoordinated rhodium(III) aqua and nitrate complexes.[3] A number of other rhodium nitrates have been characterized by X-ray crystallography: Rb4[trans-[Rh(H2O)2(NO3)4][Rh(NO3)6][4] and Cs2[-[Rh(NO3)5].[5] Rhodium nitrates are of interest because nuclear wastes, which contain rhodium, are recycled by dissolution in nitric acid.[6]

Quick facts Names, Identifiers ...
Rhodium(III) nitrate[1][2]
Names
Other names
  • Rhodium trinitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.348 Edit this at Wikidata
EC Number
  • 233-397-6
  • InChI=1S/3NO3.Rh/c3*2-1(3)4;/q3*-1;+3
    Key: VXNYVYJABGOSBX-UHFFFAOYSA-N
  • [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Rh+3]
Properties
Rh(NO3)3
Molar mass 288.92 g/mol
Appearance Yellow solid
Density 1.41 g/cm3
Soluble
Structure
Hexagonal[3]
Hazards
GHS labelling:
GHS03: OxidizingGHS05: CorrosiveGHS08: Health hazardGHS09: Environmental hazard
Danger
H271, H290, H302, H314, H317, H341, H410
P201, P202, P210, P220, P221, P234, P260, P264, P270, P272, P273, P280, P281, P283, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P306+P360, P308+P313, P310, P321, P330, P333+P313, P363, P370+P378, P371+P380+P375, P390, P391, P404, P405, P501
Related compounds
Other anions
Rhodium(III) sulfate
Other cations
Cobalt(III) nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Uses

Rhodium(III) nitrate is used as a precursor to synthesize rhodium.[7]

References

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