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Ruthenium(II) chloride

Chemical compound From Wikipedia, the free encyclopedia

Ruthenium(II) chloride is an inorganic compound with the chemical formula RuCl
2
. It forms a deep blue solution.[1]

Quick facts Names, Identifiers ...
Ruthenium(II) chloride
Names
Other names
  • Ruthenium dichloride
  • Dichlororuthenium
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/2ClH.Ru/h2*1H;/q;;+2/p-2
    Key: DHCWLIOIJZJFJE-UHFFFAOYSA-L
  • Cl[Ru]Cl
Properties
Cl2Ru
Molar mass 171.97 g·mol−1
Appearance brown crystals
poorly soluble
Solubility soluble in ethanol
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis

Ruthenium(II) chloride can be prepared by reacting ruthenium metal with dry chlorine at 250 °C:[2]

Ru + Cl2 → RuCl2

It can also be prepared by treating a ruthenium trichloride solution with hydrogen in the presence of platinum black:[1]

2RuCl3 + H2 → 2RuCl2 + 2HCl

Reactions

Ruthenium(II) chloride forms complexes with aromatic hydrocarbons.[3]

The compound can be reduced to elemental ruthenium by hydrogen.

References

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