Salt deformation

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Adits in deformed rock salt. Salt mine of Altaussee, Austria

Salt deformation is the change of shape of natural salt bodies in response to forces and mechanisms that controls salt flow. Such deformation can generate large salt structures such as underground salt layers, salt diapirs or salt sheets at the surface. Strictly speaking, salt structures are formed by rock salt that is composed of pure halite (NaCl) crystal. However, most halite in nature appears in impure form, therefore rock salt usually refers to all rocks that composed mainly of halite, sometimes also as a mixture with other evaporites such as gypsum and anhydrite.[1] Earth's salt deformation generally involves such mixed materials.

Due to the unique physical and chemical properties of rock salt such as its low density, high thermal conductivity and high solubility in water, it deforms distinctively in underground and surface environments compared with other rocks. Instability of rock salt is also given by its low viscosity, which allows rock salt to flow as a fluid. As the rock salt flows, a variety of salt structures are formed. Therefore, basins containing salt deform more easily than those lacking salt.[1]

Density and buoyancy

Rock salt from Pakistan's Khewra Salt Mine. Rock salt from this salt mine is composed of 99% pure halite.[2] The pink colour comes from the trace amounts of iron.[3]

Rock salt has an effective porosity of nearly 50% on the surface, while the effective porosity decreases to less than 10% at a depth of 10 m.[4][5] When the burial depth reaches about 45 m, the pore spaces are completely filled.[4][5] After rock salt losses its porosity, it becomes almost incompressible and keeps a constant density of 2.2 g/cm3 as the depth continue to increase.[6]

When rock salt reaches a depth of 6–8 km, other rocks are metamorphosed into greenschist. At such burial depths, the density of rock salt is slightly decreased as a result of thermal expansion. However, unlike rock salt, as the burial depth increases, shale and most other sedimentary rocks decrease in porosity and increase in density progressively. In the first 1000 m of burial depth, rock salt has a higher density compared with other rocks such as shale. When the buried material reaches a critical depth of 1.2-1.3 km, the density of rock salt and other rocks are roughly the same, where neutral buoyancy is reached. Starting from 1.3-1.5 km below the surface, the density of other rocks exceeds that of rock salt, density inversion takes place, meaning that salt has positive buoyancy when buried under other rocks at around 1.3 km. At this depth, salt rises and intrudes into the overburden, forming a diapir.[6]

Thermal conductivity and expansivity

Rock salt is characterized by its high thermal conductivity. For example, at 43 °C, it has a thermal conductivity of 5.13 W/(m⋅K), while shale only has a thermal conductivity of 1.76 W/(m⋅K) at the same temperature.[6]

The volume of rock salt can be largely affected by thermal gradient. When rock salt is buried underground at 5 km at a thermal gradient of 30 °C/km, its volume expands by 2% due to thermal expansion, while pressurization only causes volume reduction of 0.5%. Therefore, the larger the burial depth of rock salt, the lower the density of it, which in turns favors the positive buoyancy induced by density inversion.[6]

Heat can also lead to the internal flow of rock salt. When the burial depth of rock salt is over 2.9 km at a thermal gradient of 30 °C/km with viscosity below 1016 Pa.s, a flow of rock salt by thermal conduction occurs. However thermal conduction is not the dominant mechanism of salt flow in a sedimentary basin, which is completely different from the flow of magma. Salt flows at the surface if it is sufficiently wet, for instance, the flow of salt glaciers,[7] which is an exposed structure formed when a salt diapir pierces through its overburden.[8]

Viscosity

Viscosity is a measure of the resistance of fluids to flow that can be represented by the ratio of shear stress to shear strain. High viscosity means a high resistance to flow and vice versa. Experimental results show that rock salt has a higher viscosity compare with bittern and rhyolite lava, but lower viscosity than mud rock, shale, and mantle. Besides, the viscosity of rock salt is closely related to the water content. The more the water content in rock salt, the lower its viscosity.[6]

When salt glaciers feed from diapir is exposed at the surface and is infiltrated by meteoric water, the viscosity of rock salt is reduced. Consequently, the flow rate of salt glaciers is much faster than that of salt tongue spreading and salt diapir rise.[6]

In general, fine-grained wet salt flows as a Newtonian fluid, unlike coarse-grained salt. Otherwise, it will spread due to gravitational force as it extrudes to the surface.[6]

Strength

Figure showing the central blue subgrain before rotation recrystallisation (upper part) and after rotation recrystallisation (lower part). The central subgrain is re-orientated. The central black line in each subgrain indicates their orientations. An angle difference in crystal lattice between the central grain and the surrounding grains is created during this process.
Figure showing grain boundary migration. The central crystal X has a lower dislocation density then the surrounding crystal A-F. When the surrounding grains are re-orientated to match the crystal lattice of crystal X, this results in moving of grain boundary.

When stress is applied, rock salt behaves like a fluid, while other rocks of higher strength are brittle under such conditions.[9] When comparing the tensional and compressional strength of wet salt and dry salt with other typical rocks at a strain rate of 10−14s−1, such as shale and quartzite, both wet and dry salt shows lower strength than the other rocks.[10] Wet salt is even weaker than dry salt: when the water content of rock salt exceeds 0.01%, the rock salt behaves as weak crystalline fluid. Therefore, wet salt deforms more easily compare with dry salt.[11]

Salt deformation mechanism

Subgrain rotation recrystallization

Subgrain rotation recrystallization involves formation of new grain boundary as the subgrain rotates gradually and forms an angle between the surrounding crystals. A new crystal is created from mis-orientation of a subgrain.[12] The process is dominant in the top and middle part of a salt glacier.[13]

Grain-boundary migration

Grain-boundary migration is a dominant deformation mechanism at the top and the middle part of the salt glacier.[13] A subgrain is re-orientated to match the crystal lattice of the adjacent subgrain. Grain boundaries will move as the surrounding crystals are gradually consumed.[12]

Pressure-solution

Pressure-solution involves dissolution of crystals, it becomes the main deformation mechanism when salt is wetted.[1] This process are usually observed at distal part of a salt glacier.[14]

Salt dynamics

See also

References

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