Sodalite group

Mineral group From Wikipedia, the free encyclopedia

The sodalite group is a mineral group of feldspathoid minerals with a zeolitic[2] crystal structure similar to that of the eponymous sodalite. In zeolite chemistry, the sodalite structure is abbreviated as SOD.[citation needed]

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Sodalite group
General
CategoryTectosilicate minerals
GroupFeldspathoid group
IMA statusMineral group
Identification
References[1]
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Structure

The primary structure of sodalite-group minerals is a framework of truncated octahedral aluminosilicate "cages" surrounding smaller extra-framework anions and cations that serve to balance the charge. Specific ions are characteristic of specific members of the group, with partial substitution giving rise to varities such as hackmanite.[1]

Members

The sodalite group includes the following minerals:[3]

  • HaüyneNa3Ca(Si3Al3)O12(SO4)
  • SodaliteNa4(Al3Si3)O12Cl
  • NoseanNa8(Al6Si6)O24(SO4)·H2O
  • LazuriteNa3Ca(Si3Al3)O12S
  • TsaregorodtseviteN(CH3)4Si4(SiAl)O12
  • TugtupiteNa4BeAlSi4O12Cl
  • VladimirivanoviteNa Na6Ca2[Al6Si6O24](SO4,S3,S2,Cl)2·H2O

The characteristic blue color of sodalite-group minerals arises mainly from caged S3 and S4 clusters.[4]

References

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