Sodium acetylacetonate

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Sodium acetylacetonate
Names
IUPAC name
Sodium (Z)-4-oxopent-2-en-2-olate
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C5H8O2.Na/c1-4(6)3-5(2)7;/h3,6H,1-2H3;/q;+1/p-1/b4-3-;
    Key: AIWZOHBYSFSQGV-LNKPDPKZSA-M
  • C/C(=C/C(=O)C)/[O-].[Na+]
Properties
C5H7NaO2
Molar mass 122.099 g·mol−1
Appearance white solid
Melting point 210 °C (410 °F; 483 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Sodium acetylacetonate is an organic compound with the nominal formula Na[CH(C(O)CH3)2]. This white, water-soluble solid is the conjugate base of acetylacetone.[1]

The compound is prepared by deprotonation of acetylacetone: [2]

NaOH + CH2(C(O)CH3)2 → NaCH(C(O)CH3)2 + H2O

The anhydrous compound is produced by deprotonation with sodium hydride in an aprotic solvent such as THF:[3]

NaH + CH2(C(O)CH3)2 → NaCH(C(O)CH3)2 + H2

Reactions

Structure

References

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