Strontium barium niobate

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Strontium barium niobate
Identifiers
3D model (JSmol)
EC Number
  • x=0.5: 253-383-3
  • InChI=1S/Ba.4Nb.12O.Sr/q+2;;;;;;;;;;;;;4*-1;+2
    Key: DKDQMLPMKQLBHQ-UHFFFAOYSA-N
  • x=0.5: [O-][Nb](=O)=O.[O-][Nb](=O)=O.[O-][Nb](=O)=O.[O-][Nb](=O)=O.[Sr+2].[Ba+2]
Properties
(Srx,Ba1−x)Nb2O6 for 0.32≤x≤0.82
Density 5.24-5.39 g/cm3 [1]
Melting point 1,427–1,480[2] °C (2,601–2,696 °F; 1,700–1,753 K)
Hazards
GHS labelling:
GHS07: Exclamation mark
Warning
H302, H332
P261, P264, P270, P271, P301+P312, P304+P312, P304+P340, P312, P330, P501
Structure
Tetragonal
P4bm [1]
4mm
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Strontium barium niobate is the chemical compound SrxBa1−xNb2O6 for 0.32≤x≤0.82.[1]

Strontium barium niobate is a ferroelectric material commonly used in single crystal form in electro-optics, acousto-optics, and photorefractive non-linear optics for its photorefractive properties.

Strontium barium niobate is one of the few tetragonal tungsten bronze compounds without volatile elements making it a useful system for probing structure-property relations. Strontium barium niobate is a normal ferroelectric for Barium-rich compositions and becomes a relaxor ferroelectric with increasing strontium content.[3] This has been attributed to positional disorder of the A-site cations[4] alongside incommensurate oxygen octahedral tilting.[5]

Strontium barium niobate is one of numerous ceramic materials that are known to exhibit abnormal grain growth, in which certain grains grow very large within a matrix of finer equiaxed grains. This abnormal grain growth (AGG) has significant consequences on the dielectric and electronic performance of strontium barium niobate.[6]

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