Terbium(III) bromide

Chemical compound From Wikipedia, the free encyclopedia

Terbium(III) bromide (TbBr3) is a crystalline chemical compound.[5]

Quick facts Names, Identifiers ...
Terbium(III) bromide
Terbium(III) bromide
Terbium(III) bromide
Names
IUPAC name
Terbium(III) bromide
Other names
Terbium tribromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.932 Edit this at Wikidata
EC Number
  • 238-442-3
  • InChI=1S/3BrH.Tb/h3*1H;/q;;;+3/p-3
    Key: AZNZWHYYEIQIOC-UHFFFAOYSA-K
  • [Br-].[Br-].[Br-].[Tb+3]
Properties
TbBr3
Molar mass 398.637 g/mol
Appearance white powder (hexahydrate)[1]
Density 4.62 g/cm3[2]
Melting point 827[3] °C (1,521 °F; 1,100 K)
Boiling point 1,490[4] °C (2,710 °F; 1,760 K)
soluble[4]
Hazards
GHS labelling:
GHS07: Exclamation mark
Warning
H315, H319, H335
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Production and properties

Terbiun(III) bromide can be produced by heating terbium metal or terbium(III) oxide with ammonium bromide.[6]

Tb2O3 + 6 NH4Br → 2 TbBr3 + 6 NH3 + 3 H2O

A solution of terbium(III) bromide can crystallize as a hexahydrate. When heating the hexahydrate, it will dehydrate and produce some terbium oxybromide (TbOBr).[7]

Terbium(III) bromide is a white solid that is soluble in water.[4] Its crystal structure is the same as bismuth iodide.[8]

References

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