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Tetraethylammonium cyanide

Chemical compound From Wikipedia, the free encyclopedia

Tetraethylammonium cyanide is the organic compound with the formula [(CH3CH2)4N]CN. It is a "quat salt" of hydrogen cyanide. It consists of tetraethylammonium cations [(CH3CH2)4N]+ and cyanide anions CN−. This salt is a colorless, deliquescent solid that is soluble in polar organic media. It is used in the synthesis of cyanometallates.[1]

Quick facts Identifiers, Properties ...
Tetraethylammonium cyanide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.228 Edit this at Wikidata
EC Number
  • 236-566-2
  • InChI=1S/C8H20N.CN/c1-5-9(6-2,7-3)8-4;1-2/h5-8H2,1-4H3;/q+1;-1
    Key: PCZOZSATUTWXIC-UHFFFAOYSA-N
  • CC[N+](CC)(CC)CC.[C-]#N
Properties
[(CH3CH2)4N]CN
Molar mass 156.273 g·mol−1
Appearance white solid
Melting point 254 °C (489 °F; 527 K)
Hazards
GHS labelling:
GHS06: ToxicGHS09: Environmental hazard
Danger
H300, H310, H330, H410
P260, P262, P264, P270, P271, P273, P280, P284, P301+P310, P302+P350, P304+P340, P310, P320, P321, P330, P361, P363, P391, P403+P233, P405, P501
Related compounds
Other anions
Other cations
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tetraethylammonium cyanide is prepared by ion exchange from tetraethylammonium bromide. The corresponding tetraphenylarsonium salt is prepared similarly.[2]

Safety

The salt is highly toxic as it contains cyanide ions.

See also

References

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