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Tetramethylammonium ozonide

Chemical compound From Wikipedia, the free encyclopedia

Tetramethylammonium ozonide is an oxygen rich compound with the chemical formula [(CH3)4N]O3. It consists of tetramethylammonium cations ([(CH3)4N]+) and ozonide anions (O3). The compound is a free radical with one unpaired electron.[1]

Quick facts Names, Identifiers ...
Tetramethylammonium ozonide
Names
IUPAC name
Tetramethylammonium ozonide
Identifiers
3D model (JSmol)
  • InChI=1S/C4H12N.HO3/c1-5(2,3)4;1-3-2/h1-4H3;1H/q+1;/p-1
    Key: ANSRPZDTFLHQDZ-UHFFFAOYSA-M
  • C[N+](C)(C)C.[O-]O[O]
Properties
[(CH3)4N][O3]
Molar mass 122.14 g/mol−1
Appearance transparent red crystals
Melting point 75 °C (decomposition)
Related compounds
Other cations
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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It can be created through the metathesis reaction with caesium ozonide (CsO3) in a liquid ammonia solution.[2]

CsO3 + [(CH3)4N][O2] → CsO2 + [(CH3)4N][O3]

Tetramethylammonium ozonide was found to be stable; it forms into transparent red crystals, and only decomposes above 75 °C.[3]

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