Tripropylene
Chemical compound
From Wikipedia, the free encyclopedia
Tripropylene, also known as propylene trimer, is usually sold as a mixture of structural isomers of nonene.[2] This mixture is obtained by oligomerization of propene:
- 3 C3H6 → C9H18
| Identifiers | |
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3D model (JSmol) |
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| ChemSpider |
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PubChem CID |
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| UN number | 2057 |
CompTox Dashboard (EPA) |
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| Properties | |
| C9H18 | |
| Molar mass | 126.24 g/mol |
| Appearance | colourless liquid |
| Density | 1.022 g/mL |
| Melting point | −93.5 °C (−136.3 °F; 179.7 K) |
| Boiling point | 156 °C (313 °F; 429 K) |
| very low | |
| Hazards | |
| Flash point | 23[1] °C (73 °F; 296 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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In this process, two double bonds are lost and one is retained as illustrated by the isomer shown in the figure. The reaction is catalyzed by acids, such as polyphosphoric acid.[3] A variety of catalysts have been explored.[4] The reaction proceeds via the formation of a carbocation ((CH3)2CH+), which attacks another propylene unit, generating a new carbocation, etc. This kind of process affords mixtures (C3H6)n.
Like other alkenes, propylene trimer is used as an alkylating agent. A number of surfactants and lubricants are produced by alkylation of aromatic substrates.
See also
- 1-Nonene - the linear analogue
