Waelz process
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The Waelz process is a method of recovering zinc and other relatively low boiling point metals from metallurgical waste (typically electric arc furnace flue dust) and other recycled materials using a rotary kiln (waelz kiln).
The zinc enriched product is referred to as waelz oxide, and the reduced zinc by product as waelz slag.
The concept of using a rotary kiln for the recovery of Zinc by volatization dates to at least 1888.[1] A process was patented by Edward Dedolph in 1910. Subsequently, the Dedpolph patent was taken up and developed by Metallgesellschaft (Frankfurt) with Chemische Fabrik Griesheim-Elektron but without leading to a production scale ready process. In 1923 the Krupp Grusonwerk independently developed a process (1923), named the Waelz process (from the German Waelzen, a reference to the motion of the materials in the kiln); the two German firms later collaborated and improved the process marketing under the name Waelz-Gemeinschaft (German for Waelz association).[2]
The process consists of treating zinc containing material, in which zinc can be in the form zinc oxide, zinc silicate, zinc ferrite, zinc sulphide together with a carbon containing reductant/fuel, within a rotary kiln at 1000 °C to 1500 °C.[1] The kiln feed material comprising zinc 'waste', fluxes and reductant (coke) is typically pelletized before addition to the kiln.[3] The chemical process involves the reduction of zinc compounds to elemental zinc (boiling point 907 °C) which volatilises, which oxidises in the vapour phase to zinc oxide. The zinc oxide is collected from the kiln outlet exhaust by filters/electrostatic precipitators/settling chambers etc.[4][3]
Kiln size is typically 50 by 3.6 metres (164 by 12 ft) long / internal diameter, with a rotation speed of around 1 rpm. The recovered dust (Waelz oxide) is enriched in zinc oxide and is a feed product for zinc smelters, the zinc reduced by-product is known as Waelz slag. Sub-optimal features of the process are high energy consumption, and lack of iron recovery (and iron rich slag).[3] The process also captures other low boiling metals in the waelz oxide including lead, cadmium and silver.[5] Halogen compounds are also present in the product oxide.[6]
Increased use of galvanised steel has resulted in increased levels of zinc in steel scrap which in turn leads to higher levels of zinc in electric arc furnace flue dusts. As of 2000, the waelz process is considered to be a "best available technology" for flue dust zinc recovery and the process is used at industrial scale worldwide.[7]
As of 2014, the Waelz process is the preferred or most widely used process for zinc recovery of zinc from electric arc furnace dust (90%).[8]
Alternative production and experimental scale zinc recovery processes include the rotary hearth treatment of pelletised zinc containing dust (Kimitsu works, Nippon Steel);[9][10] the SDHL (Saage, Dittrich, Hasche, Langbein) process, an efficiency modification of the Waelz process;[3] the "DK process" a modified blast furnace process producing pig iron and zinc (oxide) dust from blast furnace dusts, sludges and other wastes;[11] and the PRIMUS process (multi-stage zinc volatilisation furnace).[12][13]
References
- 1 2 Clay & Schoonraad 1976, p. 11.
- ↑ Harris 1936.
- 1 2 3 4 Stewart, Daley & Stephens 2000, Recovery of Zinc Oxide from secondary raw materials : New developments of the Waelz Process
- ↑ Clay & Schoonraad 1976, pp. 11, 13.
- ↑ Antrekowitsch et al. 2014, p. 118.
- ↑ Antrekowitsch et al. 2014, p. 119.
- ↑ Stewart, Daley & Stephens 2000, Recovery of Zinc Oxide from secondary raw materials : New developments of the Waelz Process.
- ↑ Antrekowitsch et al. 2014, pp. 117–118, 119.
- ↑ Oda, Hiroshi; Ibaraki, Tetsuharu; Takahashi, Masaharu (July 2002), "Dust Recycling Technology by the Rotary Hearth Furnace" (PDF), Nippon Steel Technical Report, no. 86, archived from the original (PDF) on 2014-09-03, retrieved 2014-08-30
- ↑ Oda, Hiroshi; Ibaraki, Tetsuharu; Abe, Youichi (July 2006), "Dust Recycling System by the Rotary Hearth Furnace" (PDF), Nippon Steel Technical Report, no. 94, archived from the original (PDF) on 2016-03-03, retrieved 2014-08-30
- ↑ Hillmann, Carsten; Sassen, Karl-Josef (2006), "Solutions for dusts and sludges from the BOF process" (PDF), Stahl und Eisin, 126 (11), archived from the original (PDF) on 2016-06-15, retrieved 2014-08-30
- ↑ J. L., Roth; R., Frieden; Hansmann, T.; Monai, J.; Solvi, M. (Nov 2001). "PRIMUS, a new process for recycling by-products and producing virgin iron". Revue de Métallurgie. 98 (11): 987–996. doi:10.1051/metal:2001140.
- ↑ "The PRIMUS process by Paul Wurth: cutting-edge technology for recycling iron and steel by-products by direct reduction", www.innovation.public.lu, 3 Aug 2003, archived from the original on 3 September 2014, retrieved 30 August 2014
Sources
- Clay, J.E.; Schoonraad, G.P. (Aug 1976), "Treatment of zinc silicates by the Waelz Process" (PDF), Journal of the South African Institute of Mining and Metallurgy: 11–14
- Harris, William E. (1936), "The Waelz Process", AIME Transactions, 121 Metallurgy of Lead and Zinc: 702–720
- Stewart, Donald L. (Jr.); Daley, James C.; Stephens, Robert L., eds. (2000), "Fourth International Symposium on Recycling of Metals and Engineered Materials. Part 1", Proceedings of a Symposium organized by the Recycling Committee of the Extraction & processing Division of the Light Metals Division of TMS, 22-25 Oct 2000
- Antrekowitsch, Jürgen; Steinlechner, Stefan; Unger, Alois; Rösler, Gernot; Pichler, Christoph; Rumpold, Rene (2014), "9. Zinc and Residue Recycling", in Worrell, Ernst; Reuter, Markus (eds.), Handbook of Recycling: State-of-the-art for Practitioners, Analysts, and Scientists
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