Xylachlor

Weed control herbicide From Wikipedia, the free encyclopedia

Xylachlor is a selective herbicide, used to preëmergently control annual grasses on cereals, wheat, soy and rice. It is an anilide and a (chloro)acetanilide. As of 2023 it is considered obsolete, but may still be in use.[2]

Quick facts Names, Identifiers ...
Xylachlor
Names
Preferred IUPAC name
2-chloro-N-(2,3-dimethylphenyl)-N-propan-2-ylacetamide
Other names
  • 2-chloro-N-(2-chloro-N-isopropylacet-2,3-xylidide
  • 2-chloro-N-(2,3-dimethylphenyl)-N-(1-methylethyl)acetamide
  • xylachlore
  • CL 206784; AC 206784[1]
Identifiers
3D model (JSmol)
ChemSpider
UNII
  • InChI=1S/C13H18ClNO/c1-9(2)15(13(16)8-14)12-7-5-6-10(3)11(12)4/h5-7,9H,8H2,1-4H3
    Key: UDRNNGBAXFCBLJ-UHFFFAOYSA-N
  • CC1=C(C(=CC=C1)N(C(C)C)C(=O)CCl)C
Properties
C13H18ClNO
Molar mass 239.74 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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It was manufactured by American Cyanamid under the "Combat" trademark,[2] registered in August 1979 and expired (by non-renewal) in 1986.[3]

Compared to the fellow acetanilides alachlor, acetochlor and metolachlor, xylachlor had the weakest control of pigweed and setaria, though the greatest selectivity.[4] Xylachlor is also less detrimental to sorghum, but this is offset by the need for higher application rates to achieve similar weed control.[5] It controlled annual grasses and some broadleaf weeds, and uis generally less active than pendimethalin.[1]

Xylachlor's safety is not well studied. It and the related delachlor could be toxic, or carcinogen; some software prediction programs say so (ToxTree, Vega Hub) and some disagree. (Lazar and TEST)[6]

Application

It has been formulated as a 48% w/v emulsifiable concentrate, which was in a 1979 test, applied at 2.0-6.0 kg/Ha of active ingredient, in 400 L/Ha of spray water.[1]

More information Application Rate, Crops tolerant ...
Application Rate Effects[1]
Application RateCrops tolerantWeeds controlled
4 kg/Hawheat, pea, rape, kale, radish, cowpea, chickpea, groundnut, soyabeen, cotton, kenafbromus sterilis (barren brome), avena fatua (common wild oat), alopecurus myosuroides (blackgrass / twitchgrass), senecio vulgaris (groundsel), veronica persica (speedwell), phalaris minor (small canary-grass)
1 kg/Habarley, field bean, carrot, sugar beet, maize, sorghum (with antidote), tomatopoa annua (annual bluegrass), poa trivialis (rough bluegrass / meadowgrass), oryza punctata (red rice), echinochloa crus-galli (cockspur / barnyardgrass), digitaria sanguinalis (crabgrass), amaranthus retroflexus (common tumbleweed)
0.25 kg/Haoat, onion, lettuce, sorghum, pigeon pea, sesamumHolcus lanatus (Yorkshire fog/meadow soft grass), Eleusine indica (goosegrass), Snowdenia polystachya
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In that table, 'tolerant' means the crop's vigour was reduced by less than 15%, and 'controlled' means the weed's vigour or number was reduced by more than 70%.

References

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