The species was recorded as a species in Oxford's Annals of Botany in 1895.[4] It would later be accepted as a species in 2003's Danh lục các loài thực vật Việt Nam and 2008's Flora of China.[5]
There are three published varieties, including Zanthoxylum dimorphophyllum var. dimorphophyllum which has been found with a margin of leaflet blades with spines, Zanthoxylum dimorphophyllum var. multifoliolatum (C. C. Huang) which has been found with 3 to 5 leaflets, and Zanthoxylum dimorphophyllum var. spinifolium (Rehder & E. H. Wilson) which has been found with 7 to 11 leaflets.[2] In 1997, C. C. Huang mistakenly classified Zanthoxylum dimorphophyllum as a synonym for Z. ovalifolium Wight, which is found from India to Northeast Australia, not in the same East and Southeast Asian forests that Zanthoxylum dimorphophyllum appears.[2] This classification is still found in some records.[6] Fagara dimorphophylla has previously been recorded as a possible synonym,[5] which itself was identified in 1896 though later published as "not accepted" in 2001 World Checklist of Seed Plants Database.[7]
A 2001 study on the compounds of Zanthoxylum dimorphophyllum var spinifolium, isolated five compounds including the new 6-(2',3'-dihydroxy-3'-methybutyl)-7-acetoxy-2H-1-benzopyran-2-one.[8] A 2020 study hoping to identify compounds for the purpose of pest control isolated two new coumarins from Zanthoxylum dimorphophyllum var spinifolium.[9]