Zirconium selenate

Chemical compound From Wikipedia, the free encyclopedia

Zirconium selenate is an inorganic compound with the chemical formula Zr(SeO4)2. Its tetrahydrate can be obtained by the reaction of selenic acid and a saturated aqueous solution of zirconium oxychloride octahydrate (or zirconium hydroxide[2]). The tetrahydrate belongs to the orthorhombic crystal system and is isostructural with Zr(SO4)2·4H2O. It loses water when heated and becomes anhydrous at 220-230 °C.[3] It reacts with potassium fluoride to obtain K2Zr(SeO4)2F2·3H2O.[4]

Quick facts Identifiers, Properties ...
Zirconium selenate
Identifiers
3D model (JSmol)
  • InChI=1S/2H2O4Se.Zr/c2*1-5(2,3)4;/h2*(H2,1,2,3,4);/q;;+4/p-4
    Key: CPMVSJYYYVVNKO-UHFFFAOYSA-J
  • tetrahydrate: InChI=1S/2H2O4Se.4H2O.Zr/c2*1-5(2,3)4;;;;;/h2*(H2,1,2,3,4);4*1H2;/q;;;;;;+4/p-4
    Key: QKCOGDUMQFBTED-UHFFFAOYSA-J
  • anhydrous: [Zr+4].[O-][Se](=O)(=O)[O-].[O-][Se](=O)(=O)[O-]
  • tetrahydrate: [Zr+4].[O-][Se](=O)(=O)[O-].[O-][Se](=O)(=O)[O-].O.O.O.O
Properties
Zr(SeO4)2
Appearance colourless crystals (tetrahydrate)[1]
Density 3.806 g·cm−3 (monohydrate)[1]
3.36 g·cm−3 (tetrahydrate) [2]
Boiling point 580 °C (dec.)[3]
soluble (tetrahydrate)
Related compounds
Other anions
zirconium sulfate
Other cations
hafnium selenate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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