Ammonium iodate

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Ammonium iodate
Ammonium cation
Ammonium cation
Iodate anion
Names
IUPAC name
Ammonium iodate
Other names
Iodic acid, ammonium salt
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.252 Edit this at Wikidata
EC Number
  • 236-592-4
  • InChI=1S/HIO3.H3N/c2-1(3)4;/h(H,2,3,4);1H3
    Key: ZRDJERPXCFOFCP-UHFFFAOYSA-N
  • [NH4+].[O-]I(=O)=O
Properties
NH4IO3
Molar mass 192.94 g/mol
Appearance white crystalline powder
Density 3.309 g/cm3
Melting point decomposes at 150 °C
29.883 g/L (25 °C) [1]
−62.3·10−6 cm3/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ammonium iodate is an inorganic salt which is sparingly soluble in cold, and moderately soluble in hot water, like all iodate salts, it is a strong oxidizer.

Ammonium Iodate

Ammonium iodate can be obtained by neutralising a solution of iodic acid with ammonia.[2]

HIO3 + NH3 → NH4IO3

Using its low solubility in water, it can also be precipitated from an iodate solution with an ammonium salt.

2 KIO3 + (NH4)2SO4 → 2 NH4IO3 + K2SO4

Unlike other iodates, ammonium iodate can't be prepared by dissolving iodine in an ammonium hydroxide solution, instead the highly explosive nitrogen triiodide is formed.

3 I2 + 5 NH3 → 3 NH4I + NH3·NI3

Chemical properties

Safety

References

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