Andrianovite

From Wikipedia, the free encyclopedia

FormulaNa12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O,H2O,OH)5 (original form)
Andrianovite
Andrianovite found in Russia
General
CategorySilicate mineral, Cyclosilicate
FormulaNa12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O,H2O,OH)5 (original form)
IMA symbolAdv[1]
Strunz classification9.CO.10
Dana classification64.1.2.4
Crystal systemTrigonal
Crystal classDitrigonal pyramidal (3m)
H-M symbol: (3m)
Space groupR3m
Unit cella = 14.28, c = 30.24 [Å] (approximated); Z = 3
Identification
ColorLight yellow
Crystal habitintergrowths (rims) with eudialyte
Cleavage(001), imperfect
FractureStep-like
TenacityBrittle
Mohs scale hardness5
LusterVitreous
StreakWhite
DiaphaneityTransparent
Density2.93 (measured), 3.02 (calculated)
Optical propertiesUniaxial (−)
Refractive indexnω = 1.62, nε = 1.62 (approximated)
PleochroismNone
Ultraviolet fluorescenceNo
Common impuritiesSr, Ce, Fe
References[2][3]

Andrianovite is a very rare mineral of the eudialyte group,[2] with formula Na12(K,Sr,Ce)6Ca6(Mn,Fe)3Zr3NbSi(Si3O9)2(Si9O27)2O(O,H2O,OH)5.[3][2] The original formula was extended to show the presence of cyclic silicate groups and silicon at the M4 site, according to the nomenclature of eudialyte group.[4] Andrianovite is unique among the eudialyte group in being potassium-rich (other eudialyte-group species with essential K are davinciite and rastsvetaevite[2]). It is regarded as potassium analogue of kentbrooksite,[3] but it also differs from it in being oxygen-dominant rather than fluorine-dominant.[2] Also, the coordination number of Na in this representative is enlarged from 7 to 9. The name of the mineral honors Russian mathematician and crystallographer Valerii Ivanovich Andrianov.[3]

Notes on chemistry

References

Related Articles

Wikiwand AI