Cyclopentadienylvanadium tetracarbonyl
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3D model (JSmol) |
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CompTox Dashboard (EPA) |
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| Properties | |
| Appearance | orange solid |
| Density | 1.56 g/cm3 |
| Boiling point | sublimes |
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| H301, H311, H315, H319, H330, H335 | |
| P260, P261, P264, P270, P271, P280, P284, P301+P310, P302+P352, P304+P340, P305+P351+P338, P310, P312, P320, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P403+P233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Cyclopentadienylvanadium tetracarbonyl is the organovanadium compound with the formula (C5H5)V(CO)4. An orange, diamagnetic solid, it is the principal cyclopentadienyl carbonyl of vanadium. It can be prepared by heating a solution of vanadocene under high pressure of carbon monoxide.[1] As confirmed by X-ray crystallography, the coordination sphere of vanadium consists of η5-cyclopentadienyl and four carbonyl ligands. The molecule is a four-legged piano stool complex.[2] The compound is soluble in common organic solvents. The compound has no commercial applications.