Promethocene
Chemical compound
From Wikipedia, the free encyclopedia
Promethocene is a metal-organic compound of promethium with the chemical formula Pm(C5H5)3. It is radioactive and stable in dry air. Promethocene is different from cyclopentadiene complexes of general transition metals and is considered to be ionically bonded.[1] Theoretical calculations show that its Pm natural population analysis (NPA) electronic configuration is 6s0.115d1.194f2.21.[2]
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| Names | |
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| Other names
Promethium cyclopentadienide | |
| Identifiers | |
3D model (JSmol) |
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| Properties | |
| Pm(C5H5)3 | |
| Molar mass | 340.285 |
| Appearance | yellow-orange solid[1] |
| Boiling point | 145~260 °C (10−3~10−4mmHg, sublimates) |
| Related compounds | |
Related compounds |
cyclopentadiene |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation
Promethocene can be obtained by reacting anhydrous promethium(III) chloride and sodium cyclopentadienide in a tetrahydrofuran medium:[1]
- 3C5H5Na + PmCl3 → (C5H5)3Pm + 3 NaCl
Chemical properties
Promethocene decomposes when exposed to water to produce promethium(III) hydroxide and cyclopentadiene.