Diiodobutadiyne

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Diiodobutadiyne
Names
IUPAC name
1,4-Diiodobuta-1,3-diyne
Other names
Diiododiacetylene
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C4I2/c5-3-1-2-4-6 Key:HUKBPXSFAFKZBD-UHFFFAOYSA-N
  • IC#CC#CI
Properties
C4I2
Molar mass 301.853 g·mol−1
Appearance White solid
Solubility in hexanes Soluble
Structure
Linear
Explosive data
Shock sensitivity Sensitive - may explode if struck
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Diiodobutadiyne (1,4-diiodobuta-1,3-diyne) is an organoiodine compound with the chemical formula C4I2. Its structure is I−C≡C−C≡C−I. It is a white solid. It is used in the creation of the polymer poly(diiododiacetylene) (PIDA) by undergoing 1,4 polymerization. It is a small linear molecule related to diacetylene, where the hydrogens of diacetylene is replaced by iodine.[1]

Diiodobutadiyne is light sensitive and explosive if stored out of solution as a dry solid. It will undergo random 1,2 and 1,4 polymerization, as well as decomposition in solution if kept over an extended period of time, having a half-life of just about two weeks.[2]

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