Gadolinium(III) perchlorate

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Gadolinium(III) perchlorate
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
12731
  • InChI=1S/3ClHO4.Gd/c3*2-1(3,4)5;/h3*(H,2,3,4,5);/q;;;+3/p-3
    Key: HYBHAIGYQVICOT-UHFFFAOYSA-K
  • [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Gd+3]
Properties
Cl3GdO12
Molar mass 455.59 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Gadolinium(III) perchlorate is an inorganic compound with the chemical formula Gd(ClO4)3. It can be obtained by reacting gadolinium(III) oxide and perchloric acid (70~72%) at 80 °C.[1] It can form colorless Gd(ClO4)3·9H2O·4C4H8O2 complex crystals with 1,4-dioxane.[2] It reacts with inositol, sodium acetate, and sodium hydroxide to obtain complexes containing giant molecular clusters {Gd140}.[1] It reacts with chromium(III) chloride and 2,2'-bipyridine at pH=5.1 to obtain [GdCr(bipy)2(OH)2(H2O)6](ClO4)4·2H2O.[3]

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