Potassium tetrachloropalladate(II)

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Potassium tetrachloropalladate(II)
Names
IUPAC name
dipotassium; tetra chloropalladium(2-)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.033 Edit this at Wikidata
EC Number
  • 233-049-3
  • InChI=1S/4ClH.2K.Pd/h4*1H;;;/q;;;;2*+1;+2/p-4
    Key: LGCKLDWLSVFMGL-UHFFFAOYSA-J
  • [K+].[K+].Cl[Pd--](Cl)(Cl)Cl
Properties
Cl4K2Pd
Molar mass 326.42 g·mol−1
Appearance dark brown crystals
Density 2.67 g/cm3
Melting point 525 °C
soluble
Solubility poorly soluble in ethanol and acetone[1][2]
Structure[3]
tetragonal
P 4/mmm
a = 0.706 nm, c = 0.410 nm
1 unit per cell
Hazards
GHS labelling:[4]
GHS07: Exclamation mark
Warning
P261, P305, P338, P351
Related compounds
Other cations
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Potassium tetrachloropalladate(II) is an inorganic compound with the chemical formula K2PdCl4.[5][6] It is a dark brown solid, forming tetragonal crystals.

Potassium tetrachloropalladate(II) can be prepared by passing chlorine through a palladium black suspension in a concentrated potassium chloride solution:

Pd + Cl2 + 2KCl → K2[PdCl4]

It can also be prepared by mixing concentrated solutions of palladium(II) chloride and potassium chloride:[7]

PdCl2 + 2KCl → K2[PdCl4]

It forms in the decomposition of potassium hexachloropalladate(IV):

K2[PdCl6] → K2[PdCl4] + Cl2

Uses

Reactions

References

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