Seleninyl fluoride

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Seleninyl fluoride
Names
Other names
selenium difluoride oxide
Identifiers
3D model (JSmol)
ChemSpider
UNII
  • InChI=1S/F2OSe/c1-4(2)3
    Key: CXZZMNPTKAXBFL-UHFFFAOYSA-N
  • O=[Se](F)F
Properties
F2OSe
Molar mass 132.967 g·mol−1
Appearance colourless fuming liquid[1]
Boiling point 125[1] °C (257 °F; 398 K)
Structure
3.18±0.02 D[2]
Related compounds
Other anions
selenium oxychloride
selenium oxybromide
Other cations
thionyl fluoride
Related compounds
selenium dioxydifluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Seleninyl fluoride is an oxyfluoride of selenium with the chemical formula SeOF2.

Seleninyl fluoride can be produced by the reaction of selenium oxychloride and potassium fluoride.[3]

2 KF + SeOCl2 → 2 KCl + SeOF2

It can also be produced by the reaction of selenium tetrafluoride with water or selenium dioxide.[2]

SeF4 + H2O → SeOF2 + 2 HF
SeF4 + SeO2 → 2 SeOF2

The reaction of selenium dioxide and sulfur tetrafluoride also produces seleninyl fluoride.[4]

SeO2 + SF4 → SeOF2 + SOF2

Reactions

Uses

References

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