The Very Best of Rainbow

1. "Man on the Silver Mountain" (Ritchie Blackmore, Ronnie James Dio) - 4:37 (from Ritchie Blackmore's Rainbow, 1975)
2. "Catch the Rainbow" (Blackmore, Dio) - 6:38 (from Ritchie Blackmore's Rainbow, 1975)
3. "Starstruck" (Blackmore, Dio) - 4:06 (from Rising, 1976)
4. "Stargazer" (Blackmore, Dio) - 8:26 (from Rising, 1976)
5. "Kill the King" (Blackmore, Dio, Cozy Powell) - 4:28 (from Long Live Rock 'n' Roll, 1978)
6. "Long Live Rock 'n' Roll" (Blackmore, Dio) - 4:23 (from Long Live Rock 'n' Roll, 1978)
7. "Gates of Babylon" (Blackmore, Dio) - 6:46 (from Long Live Rock 'n' Roll, 1978)
8. "Since You Been Gone" (Russ Ballard) - 3:17 (from Down to Earth, 1979)
9. "All Night Long" (Blackmore, Roger Glover) - 3:50 (from Down to Earth, 1979)
10. "I Surrender" (Ballard) - 4:01 (from Difficult to Cure, 1981)
11. "Can't Happen Here" (Blackmore, Glover) - 4:57 (from Difficult to Cure, 1981)
12. "Jealous Lover" (Blackmore, Joe Lynn Turner) - 3:11 (from Jealous Lover EP, 1981)
13. "Stone Cold" (Blackmore, Glover, Turner) - 5:17 (from Straight Between the Eyes, 1982)
14. "Power" (Blackmore, Glover, Turner) - 4:26 (from Straight Between the Eyes, 1982)
15. "Can't Let You Go" (Blackmore, Turner, David Rosenthal) - 4:20 (from Bent Out of Shape, 1983)
16. "Street of Dreams" (Blackmore, Turner) - 4:26 (from Bent Out of Shape, 1983)

Tracks 1–7 feature Ronnie James Dio on lead vocals.
Tracks 8–9 feature Graham Bonnet.
Tracks 10–16 feature Joe Lynn Turner.