Thiophosphoryl bromide
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| Names | |||
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| Other names
Thiophosphoryl tribromide Phosphorus thiobromide Phosphorothioic tribromide | |||
| Identifiers | |||
3D model (JSmol) |
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| ChemSpider | |||
| ECHA InfoCard | 100.021.367 | ||
| EC Number |
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PubChem CID |
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CompTox Dashboard (EPA) |
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| Properties | |||
| PSBr3 | |||
| Molar mass | 302.75 g·mol−1 | ||
| Appearance | yellow crystals[1][2] | ||
| Density | 2.85 g cm−3[2] | ||
| Melting point | 37.8 °C (100.0 °F; 310.9 K) | ||
| Boiling point | 212 °C (414 °F; 485 K) decomposes[2] | ||
| Structure[3] | |||
| Cubic | |||
| Pa3, No. 205 | |||
a = 11.03 Å, b = 11.03 Å, c = 11.03 Å | |||
| Tetrahedral at the P atom | |||
| Related compounds | |||
Related compounds |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Thiophosphoryl bromide is an inorganic compound with the formula PSBr3.[1]
Thiophosphoryl bromide can be prepared by heating phosphorus tribromide with phosphorus pentasulfide, or with elemental sulfur in an inert atmosphere at 130 °C.[4]
Thiophosphoryl bromide is one product of the bromination of P4S7 in cold carbon disulfide:[1]