Phosphatoantimonate
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Phosphatoantimonates are compounds that contain anions that contain phosphorus and antimony in the +5 oxidation state, along with oxygen. Thus they are a compound of phosphate and antimonate, bound together by oxygen.
phosphatoantimonates have been investigated as catalysts,[1] and ion exchange materials.[2]
| formula | mw | crystal system | space group | unit cell Å | volume | density | comment | references |
|---|---|---|---|---|---|---|---|---|
| SbOPO4 | monoclinic | C2c | a = 6.791 b = 8.033 c = 7.046 β = 115.90° Z=4 | [3] | ||||
| SbIIISbV3(PO4)6 | trigonal | R3 | a = 16.880 c = 21.196 Z=12 | 5230 | mixed valence | [4] | ||
| HSb(PO4)2·2H2O | layered; can be exfoliated; can exchange H+ with other ions; can reversibly dehydrate | [5][6] | ||||||
| H3Sb3P2O14•xH2O | layered | [7] | ||||||
| H5Sb5P2O20•xH2O | 3D with channels | [7] | ||||||
| Li5Sb5P2O20 | [8] | |||||||
| (NH4)3Sb3P2O14•3H2O | [9] | |||||||
| Na3SbO(PO4)2 | orthorhombic | P212121 | a = 6.964 b = 9.284 c = 12.425 Z = 4 | 1D | [10][11] | |||
| Na3Sb3P2O14 | [8] | |||||||
| Na5Sb5P2O20 | [8] | |||||||
| Mg0.50SbFe(PO4)3 | hexagonal | P3 | a = 8.3443 c = 22.3629 Z=6 | nasicon | [12] | |||
| KSb2PO8 | monoclinic | Cc | a=12.306 b=7.086 c=15.037 β=95.82° Z=8 | 1304.5 | 4.498 | colourless; 3D | [13][14] | |
| KSb2PO8−xNy | [15] | |||||||
| KSbP2O8 | rhombohedral | R3 | a = 4.7623 c = 25.409 Z = 3 | 2D | [13][16] | |||
| K2SbPO6 | orthorhombic | Pnma | a= 9.429 b= 5.891 c= 11.030 Z= 4 | 1D | [13][17] | |||
| 4K2O · 4Sb2O5 · P2O5 · 8H2O
K8Sb8P2O29·8H2O |
monovlinic | a = 23.952 b = 9.515 c = 8.193 β = 124.77° | 31P NMR shift −−6.77 ppm | [18][19] | ||||
| K3Sb3P2O14 | rhombohedral | R3m | a = 7.147 c = 30.936 Z = 3 | reversible hydration; 2D | [13][20] | |||
| K3Sb3P2O14, 1.32H2O | rhombohedral | R3m | a = 7.147 c = 30.936 Z=3 | [21] | ||||
| K3Sb3P2O14·5H2O | hexagonal | P3 | Z=6 | [22] | ||||
| K5Sb5P2O20 | orthorhombic | Pnnm | a= 23.443 b= 18.452 c= 7.149 z= 6 | 3D | [13][23] | |||
| K2SbAs0.5P0.5O6 | orthorhombic | [24] | ||||||
| ScSbV3(PO4)6 | monoclinic | P21/n | a=11.810 b=8.616 c=8.400 β=90.80° | 854.6 | [4] | |||
| NaSbCr(PO4)3 | rhombohedral | R3 | a = 8.329 c = 22.094 Z=6 | 1327 | nasicon | [25] | ||
| Ca0.5AlSb(PO4)3 | a=8.56 c=21.87 | 4.128 | nasicon | [26] | ||||
| Mn0.50SbFe(PO4)3 | rhombohedral | R3 | a=8.375 c=21.597 | nasicon | [27][28] | |||
| Mn0.5AlSb(PO4)3 | rhombohedral | R3c | a=8.270 c=21,799 | 3.56 | nasicon | [26] | ||
| Ca0.5CrSb(PO4)3 | a=8.61 c=22.08 | 4.321 | nasicon | [26] | ||||
| Mn0.5CrSb(PO4)3 | monoclinic | P21/n | a=12.280 b=8.814 c=8.613 β=91.03° | 3.45 | [26] | |||
| Sb1.50Fe0.50(PO4)3 | hexagonal | R32 | a=8.305 c=22.035 | [29] | ||||
| (Sb0.50Fe0.50)P2O7 | orthorhombic | Pna21 | a=7.865 b=15.699 c=7.847 | pyrophosphate | [29] | |||
| CaSb0.50Fe1.50(PO4)3 | rhombohedral | R3c | a=8.514 c=21.871 | nasicon | [30] | |||
| Ca0.50SbFe(PO4)3 | rhombohedral | R3 | a=8.257 c=22.276 | nasicon | [27][30] | |||
| Mn0.5FeSb(PO4)3 | rhombohedral | R3c | a=8.374 c=21.593 | 3.68 | nasicon | [26] | ||
| NaSbFe(PO4)3 | rhombohedral | R3 | a = 8.361 c = 22.222 Z=6 | 1345 | nasicon | [25] | ||
| Co[Sb(PO4)2]2·6H2O | [5] | |||||||
| Ni0.50SbFe(PO4)3 | hexagonal | P3 | a = 8.3384 c = 22.3456 | nasicon | [12] | |||
| Rb3Sb3P2O14 | [8] | |||||||
| Rb3Sb3P2O14•3H2O | rhombohedral | R3m | a=7.1445 c=31.802 | [9] | ||||
| Rb5Sb5P2O20 | [8] | |||||||
| Sr0.50SbFe(PO4)3 | rhombohedral | R3 | a = 8.227 c = 22.767 | nasicon | [27] | |||
| SrSb0.50Cr0.50(PO4)2 | monoclinic | C2/c | a= 16.5038 b= 5.1632 c= 8.0410 β = 115.85° Z=4 | 617 | yavapaiite | [31] | ||
| SrSb0.50Fe1.50(PO4)3 | rhombohedral | R3c | a = 8.339 c = 22.704 | nasicon | [27] | |||
| Sr(SbV0.50FeIII0.50)(PO4)2 | monoclinic | C2/c | a = 16.5215 b = 5.1891 c = 8.0489 β = 115.70° Z=4 | yavapaiite | [32] | |||
| Sr(Ga0.5Sb0.5)(PO4)2 | monoclinic | C2/c | a=16.455; b=5.158 c= 8.005 β=115.49° Z=4 | 613 | [33] | |||
| YSbV3(PO4)6 | R3 | a=17.019 c=21.233 | 5326 | [4] | ||||
| Cd0.50SbFe(PO4)3 | rhombohedral | R3 | a=8.313 c=21.996 | nasicon | [27][28] | |||
| SbV1.50InIII0.50(PO4)3 | monoclinic | P21/n | a=11.801 b=8.623 c=8.372 β=90.93° | [34] | ||||
| SbV0.50InIII0.50P2O7 | orthorhombic | Pna21 | a=7.9389 b=16.0664 c=7.9777 | pyrophosphate | [34] | |||
| InSbV3(PO4)6 | monoclinic | P21/n | a=11.792 b=8.622 c=8.379 β=90.91° | 851.8 | [4] | |||
| NaSbIn(PO4)3 | rhombohedral | R3 | a=8.329 c = 23.031 Z=6 | 1383 | nasicon | [25] | ||
| Cs3Sb3P2O14•3H2O | rhombohedral | R3m | a=7.153 c=32.840 | [9] | ||||
| Cs4MgSb6P4O28 | 1858.39 | tetragonal | I41/a | a=16.5170 c=10.7355 Z=4 | 2928.8 | 4.22 | band gap 4.50 eV | [35] |
| Cs4ZnSb6P4O28 | tetragonal | I41/a | a=16.4821 c=10.7453 Z=4 | 2919.1 | 4.32 | band gap 4.48 eV | [35] | |
| K0.8Ba1.6Sb4O9(PO4)2 (0 < x < 0.4) | orthorhombic | Pnma | a = 20.998 b = 7.168 c = 9.569 | [36] | ||||
| Ba2Sb4O9(PO4)2 | orthorhombic | Pnma | a = 20.9237 b = 7.1836 c = 9.5189 Z = 4 | [36] | ||||
| BaSb0.50Cr0.50(PO4)2 | monoclinic | C2/m | a= 8.140 b= 5.175 c= 7.802 β = 94. 387° Z=2 | 328 | yavapaiite | [31] | ||
| BaSb2/3Mn1/3(PO4)2 | monoclinic | C2/m | a= b= c=7.8808 β=94.4° Z=2 | 337 | [37] | |||
| Ba(Sb0.50FeIII0.50)(PO4)2 | monoclinic | C2/m | a = 8.1568 b = 5.1996 c = 7.8290 β = 94.53° Z=2 | yavapaiite | [32] | |||
| BaSb2/3Co1/3(PO4)2 | monoclinic | C2/m | c=7.8581 β=94.7° Z=2 | 333 | [37] | |||
| BaSb2/3Cu1/3(PO4)2 | monoclinic | C2/m | c=7.8795 β=95.3° Z=2 | 331 | [37] | |||
| BaSb2/3Zn1/3(PO4)2 | monoclinic | C2/m | c=7.8497 β=94.8° Z=2 | 332 | [37] | |||
| Ba(Ga0.5Sb0.5)(PO4)2 | monoclinic | C2/m | a= 8.106 b= 5.178 c= 7.806 β=94.79° Z=2 | 327 | [33] | |||
| Tl3Sb3P2O14•3H2O | rhombohedral | R3m | a=7.135 c=31.447 | [9] | ||||
| PbSb0.50Cr0.50(PO4)2 | monoclinic | C2/c | a= 16.684 b= 5.156 c= 8.115 β = 115.35° Z=4 | 631 | yavapaiite | [31] | ||
| Pb(Sb0.50FeIII0.50)(PO4)2 | monoclinic | C2/c | a = 16.6925 b = 5.1832 c = 8.1215 β = 115.03° | yavapaiite | [32] | |||
| PbSb0.50Fe1.50(PO4)3 | rhombohedral | R3c | a = 8.313 c = 23.000 Z=6 | 1377 | nasicon | [38] | ||
| Pb0.50SbFe(PO4)3 | rhombohedral | R3 | a = 8.2397 c = 22.7801 Z=6 | 1339 | nasicon | [38] | ||
| Pb(Ga0.5Sb0.5)(PO4)2 | monoclinic | C2/c | a=16.622 b=5.163 c=8.067 β=114.85° | 628 | [33] | |||
| BiSbV3(PO4)6 | trigonal | R3 | a=17.034 c=21.260 | 5342.1 | [4] | |||
| CaSb0.50Bi1.50(PO4)3 | monoclinic | P21/m | a = 4.9358 b = 6.9953 c = 4.7075 β = 96.2° | [39] |
References
- ↑ Natarajan, Srinivasan; Thomas, John M. (February 1992). "The search for new solid acid catalysts: systems derived from phosphatoantimonates". Catalysis Today. 12 (4): 433–441. doi:10.1016/0920-5861(92)80060-Z.
- ↑ Guo, Yan-Ling; Sun, Hai-Yan; Zeng, Xi; Lv, Tian-Tian; Yao, Yue-Xin; Zhuang, Ting-Hui; Feng, Mei-Ling; Huang, Xiao-Ying (March 2023). "Efficient removal of Sr2+ ions by a one-dimensional potassium phosphatoantimonate". Chemical Engineering Journal. 460 141697. doi:10.1016/j.cej.2023.141697.
- ↑ Piffard, Y.; Oyetola, S.; Verbaere, A.; Tournoux, M. (June 1986). "Synthesis, thermal stability, and crystal structure of antimony(V) phosphate SbOPO4". Journal of Solid State Chemistry. 63 (1): 81–85. doi:10.1016/0022-4596(86)90155-6.
- 1 2 3 4 5 Kasahara, Kenzo; Imoto, Hideo; Saito, Taro (August 1995). "Preparation and Crystal Structure of a New Form of Sb2(PO4)3 and M1/2SbV3/2(PO4)3 (M = Y, In, and Sc)". Journal of Solid State Chemistry. 118 (1): 104–111. doi:10.1006/jssc.1995.1317.
- 1 2 Hudson, Michael J.; Locke, William; Mitchell, Philip C. H. (1995). "Ion-exchange and protonic species in the antimony hydrogen phosphate HSb(PO 4 ) 2 ·2H 2 O". J. Mater. Chem. 5 (1): 159–163. doi:10.1039/JM9950500159. ISSN 0959-9428.
- ↑ Prasad, G.K.; Kumada, N.; Yamanaka, J.; Yonesaki, Y.; Takei, T.; Kinomura, N. (May 2006). "Lamellar nanocomposites based on exfoliated nanosheets and ionic polyacetylenes". Journal of Colloid and Interface Science. 297 (2): 654–659. Bibcode:2006JCIS..297..654P. doi:10.1016/j.jcis.2005.11.004. PMID 16364352.
- 1 2 Deniard-Courant, S (July 1988). "Relative humidity influence on the water content and on the protonic conductivity of the phosphatoantimonic acids HnSbnP2O3n+5, xH2O (n = 1, 3, 5)". Solid State Ionics. 27 (3): 189–194. doi:10.1016/0167-2738(88)90009-4.
- 1 2 3 4 5 Wang, E.; Greenblatt, M. (1991-07-01). "Ionic conductivities of ion-exchanged alkali metal phosphatoantimonate (A2Sb3P2O14, A = sodium, potassium, rubidium), A5Sb5P2O20 (A =lithium, sodium, potassium, rubidium), and partially substituted potassium phosphatoantimonato niobate or potassium phosphatoantimonato tantalate (K5Sb5-xMxP2O20, M = niobium, tantalum)". Chemistry of Materials. 3 (4): 703–709. doi:10.1021/cm00016a026. ISSN 0897-4756.
- 1 2 3 4 Walko, Priyanka S.; Paidi, Anil Kumar; Vidyasagar, Kanamaluru (2017-12-11). "Syntheses and Structural Characterization of A 3 Sb 3 P 2 O 14 ⋅3H 2 O ( A =Rb, Cs, Tl and NH 4 ) Phosphates; Facile Aqueous Ion Exchange Reactions of K 3 Sb 3 P 2 O 14 ⋅3H 2 O". ChemistrySelect. 2 (35): 11875–11879. doi:10.1002/slct.201702401. ISSN 2365-6549.
- ↑ Velchuri, Radha; Kadari, Ramaswamy; Ravi, Gundeboina; Munirathnam, Nagegownivari R.; Vithal, Muga (April 2015). "Effect of Cation/Anion Co-doping on the Photocatalytic Performance of Na 3 SbO(PO 4 ) 2". Zeitschrift für anorganische und allgemeine Chemie. 641 (5): 935–940. Bibcode:2015ZAACh.641..935V. doi:10.1002/zaac.201400557. ISSN 0044-2313.
- ↑ Guyomard, D.; Pagnoux, C.; Letho, J.J.Zah; Verbaere, A.; Piffard, Y. (February 1991). "Preparation and crystal structure of Na3SbO(PO4)2". Journal of Solid State Chemistry. 90 (2): 367–372. doi:10.1016/0022-4596(91)90154-A.
- 1 2 Aatiq, Abderrahim; Marchoud, Asmaa; Bellefqih, Hajar; Tigha, My Rachid (September 2017). "Structural and Raman spectroscopic studies of the two M 0.50 SbFe(PO 4 ) 3 ( M = Mg, Ni) NASICON phases". Powder Diffraction. 32 (S1): S40 – S51. Bibcode:2017PDiff..32S..40A. doi:10.1017/S0885715617000331. ISSN 0885-7156.
- 1 2 3 4 5 Husson, E.; Genet, F.; Lachgar, A.; Piffard, Y. (August 1988). "The vibrational spectra of some antimony phosphates". Journal of Solid State Chemistry. 75 (2): 305–312. Bibcode:1988JSSCh..75..305H. doi:10.1016/0022-4596(88)90171-5.
- ↑ Piffard, Y.; Lachgar, A.; Tournoux, M. (June 1985). "Crystal structure of KSb2PO8". Materials Research Bulletin. 20 (6): 715–721. doi:10.1016/0025-5408(85)90150-3.
- ↑ Ravi, G.; Sudhakar Reddy, Ch.; Sreenu, K.; Guje, Ravinder; Velchuri, Radha; Vithal, M. (April 2016). "Degradation of Methylene Blue and Rhodamine B Using a New Visible Light-Responsive Photocatalyst, KSb2PO8−x N y". Acta Metallurgica Sinica (English Letters). 29 (4): 335–343. doi:10.1007/s40195-016-0401-6. ISSN 1006-7191.
- ↑ Piffard, Y.; Oyetola, S.; Courant, S.; Lachgar, A. (November 1985). "Crystal structure of KSbP2O8". Journal of Solid State Chemistry. 60 (2): 209–213. doi:10.1016/0022-4596(85)90114-8.
- ↑ Lachgar, A.; Deniard-Courant, S.; Piffard, Y. (July 1986). "Preparation and crystal structure of K2SbPO6". Journal of Solid State Chemistry. 63 (3): 409–413. doi:10.1016/0022-4596(86)90198-2.
- ↑ An, Yonglin; Feng, Shouhua; Xu, Yihua; Xu, Ruren; Yue, Yong (November 1994). "Hydrothermal synthesis and characterization of a new potassium phosphatoantimonate". Journal of Materials Research. 9 (11): 2745–2746. Bibcode:1994JMatR...9.2745A. doi:10.1557/JMR.1994.2745. ISSN 0884-2914.
- ↑ An, Yonglin; Feng, Shouhua; Xu, Yihua; Xu, Ruren; Yue, Yong (1996-01-01). "Hydrothermal Synthesis and Characterization of a New Potassium Phosphatoantimonate, K 8 Sb 8 P 2 O 29 ·8H 2 O". Chemistry of Materials. 8 (2): 356–359. doi:10.1021/cm950182+. ISSN 0897-4756.
- ↑ Piffard, Y.; Lachgar, A.; Tournoux, M. (July 1985). "Structure cristalline du phosphatoantimonate K3Sb3P2O14". Journal of Solid State Chemistry (in French). 58 (2): 253–256. doi:10.1016/0022-4596(85)90242-7.
- ↑ Lachgar, A.; Deniard-Courant, S.; Piffard, Y. (April 1988). "Adsorption and structural studies of water in the layered compounds K3Sb3M2O14, xH2O (M = P, As)". Journal of Solid State Chemistry. 73 (2): 572–576. doi:10.1016/0022-4596(88)90147-8.
- ↑ An, Yonglin; Feng, Shouhua; Xu, Yihua; Xu, Ruren; Yue, Yong (1995). "Hydrothermal synthesis and characterization of K 3 Sb 3 A 2 O 14 ·5H 2 O (A P,As)". J. Mater. Chem. 5 (5): 773–776. doi:10.1039/JM9950500773. ISSN 0959-9428.
- ↑ Piffard, Y.; Lachgar, A.; Tournoux, M. (October 1986). "A potassium phosphatoantimonate with a three dimensional framework : K5Sb5P2O20". Materials Research Bulletin. 21 (10): 1231–1238. doi:10.1016/0025-5408(86)90052-8.
- ↑ Botto, I.L.; Garcia, A.C. (December 1989). "Crystallographic data and vibrational spectrum of K2SbAsO6". Materials Research Bulletin. 24 (12): 1431–1439. doi:10.1016/0025-5408(89)90153-0.
- 1 2 3 Aatiq, Abderrahim; Tigha, My Rachid (September 2013). "Structural and spectroscopic study of NaSbR(PO 4 ) 3 (R = Cr, Fe, In) phases". Powder Diffraction. 28 (S2): S394 – S408. Bibcode:2013PDiff..28S.394A. doi:10.1017/S0885715613000882. ISSN 0885-7156.
- 1 2 3 4 5 Anantharamulu, Navulla; Rao, K. Koteswara; Vithal, M.; Prasad, G. (June 2009). "Preparation, characterization, impedance and thermal expansion studies of Mn0.5MSb(PO4)3 (M=Al, Fe and Cr)". Journal of Alloys and Compounds. 479 (1–2): 684–691. doi:10.1016/j.jallcom.2009.01.038.
- 1 2 3 4 5 Aatiq, Abderrahim; Tigha, My Rachid; Benmokhtar, Said (February 2012). "Structure, infrared and Raman spectroscopic studies of new Sr0.50SbFe(PO4)3 and SrSb0.50Fe1.50(PO4)3 Nasicon phases". Journal of Materials Science. 47 (3): 1354–1364. Bibcode:2012JMatS..47.1354A. doi:10.1007/s10853-011-5910-0. ISSN 0022-2461.
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- 1 2 Aatiq, Abderrahim; Bakri, Rachid (March 2007). "Crystal structures of newly synthesized Sb V 1.50 Fe III 0.50 (PO 4 ) 3 and (Sb V 0.50 Fe III 0.50 )P 2 O 7". Powder Diffraction. 22 (1): 47–54. doi:10.1154/1.2434788. ISSN 0885-7156.
- 1 2 Aatiq, Abderrahim; Tigha, My Rachid; Hassine, Rabia; Saadoune, Ismael (March 2006). "Crystallochemistry and structural studies of two newly CaSb 0.50 Fe 1.50 (PO 4 ) 3 and Ca 0.50 SbFe(PO 4 ) 3 Nasicon phases". Powder Diffraction. 21 (1): 45–51. doi:10.1154/1.2104535. ISSN 0885-7156.
- 1 2 3 Bellefqih, Hajar; Fakhreddine, Rachid; Tigha, Rachid; Aatiq, Abderrahim (2020). "Structure, Infrared and Raman spectroscopic studies of new AII(SbV0.50CrIII0.50)(PO4)2 (A = Ba, Sr, Pb) yavapaiite phases". Mediterranean Journal of Chemistry. 10 (8): 734–743. doi:10.13171/mjc10802108201448hb. S2CID 225277143.
- 1 2 3 Aatiq, Abderrahim; Tigha, My Rachid; Fakhreddine, Rachid; Bregiroux, Damien; Wallez, Gilles (August 2016). "Structure, infrared and Raman spectroscopic studies of newly synthetic AII(SbV0.50FeIII0.50)(PO4)2 (ABa, Sr, Pb) phosphates with yavapaiite structure". Solid State Sciences. 58: 44–54. doi:10.1016/j.solidstatesciences.2016.05.009.
- 1 2 3 Fakhreddine, Rachid; Ouasri, Ali; Aatiq, Abderrahim (January 2024). "Synthesis, structural, morphology, spectroscopic and optical study of new metal orthophosphate MII(Ga0.5Sb0.5)(PO4)2 (MII= Sr, Pb, Ba) compounds". Journal of Solid State Chemistry. 329 124439. doi:10.1016/j.jssc.2023.124439.
- 1 2 Aatiq, Abderrahim; Bakri, Rachid; Sakulich, Aaron Richard (September 2008). "Preparation and crystal structure of Sb V 1.50 In III 0.50 (PO 4 ) 3 and (Sb V 0.50 In III 0.50 )P 2 O 7". Powder Diffraction. 23 (3): 232–240. doi:10.1154/1.2955583. ISSN 0885-7156.
- 1 2 Zhang, Wei-Long; Guo, Zhen-Gang; Guan, Xiang-Feng; Chen, Chinghwa; He, Jiangang; Luo, Pei-Hui; Li, Xiao-Yan; Ding, Feng-Hua; Cheng, Wen-Dan (2019-05-27). "Unique 3D framework formed by adding M II O 4 groups into high Sb/P ratio phosphatoantimonates". Zeitschrift für Kristallographie - Crystalline Materials. 234 (5): 301–306. doi:10.1515/zkri-2018-2137. ISSN 2196-7105.
- 1 2 Pagnoux, C.; Mar, A.; Verbaere, A.; Piffard, Y. (February 1995). "Synthesis and Structure of K2xBa2-xSb4O9(PO4)2 (0 < x < 0.4)". Journal of Solid State Chemistry. 114 (2): 399–405. doi:10.1006/jssc.1995.1061.
- 1 2 3 4 Bellefqih, H.; Bilal, E.; Fakhreddine, R.; Mehdaoui, B.; Haneklaus, N.; Aatiq, A. (May 2024). "Structural, vibrational, and optical studies of newly synthesized Yavapaiite-type phases BaSb2/3X1/3(PO4)2 (X = Mn, Co, Cu, Zn)". Inorganic Chemistry Communications. 163 112347. doi:10.1016/j.inoche.2024.112347.
- 1 2 "Structure and spectroscopic characterization of the two PbSb0.5Fe1.5(PO4)3 and Pb0.5SbFe(PO4)3 phosphates with Nasicon type-structure". J. Mater. Environ. Sci. 6 (12): 3483–3490. 2015.
- ↑ Aatiq, Abderrahim; Tigha, My Rachid (March 2014). "Structure of a new Ca II 1/3 Sb V 1/6 Bi III 1/2 PO 4 phosphate". Powder Diffraction. 29 (1): 14–19. Bibcode:2014PDiff..29...14A. doi:10.1017/S0885715613000717. ISSN 0885-7156.
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