Phosphate sulfate
From Wikipedia, the free encyclopedia
Compound with phosphate and sulfate ions
The phosphate sulfates are mixed anion compounds containing both phosphate and sulfate ions. Related compounds include the arsenate sulfates, phosphate selenates, and arsenate selenates.
Some hydrogen phosphate sulfates are superprotonic conductors.
| chem | mw | crystal system | space group | unit cell | volume | density | comment | references | |
|---|---|---|---|---|---|---|---|---|---|
| Sanjuanite | Al2(PO4)(SO4)(OH)·9H2O | [1] | |||||||
| Hotsonite | Al11(SO4)3(PO4)2(OH)21 · 16H2O | triclinic | a=11.23, b=11.66 c=10.55 α=112° 32′, β=107° 32′ γ=64° 27′ | refract: α = 1.519 γ = 1.521 | [2] | ||||
| Arangasite | Al2F(PO4)(SO4)·9H2O | monoclinic | P2/a | a = 7.073, b = 9.634, c = 10.827, β = 100.40°, Z = 2 | 725.7 | [3] | |||
| peisleyite | Na3Al16(SO4)2(PO4)10(OH)17 · 20H2O | monoclinic | a 13.31, b 12.62, c 23.15, β 110.0°, Z = 2 | discredited | [4] | ||||
| peisleyite | Na2Al9[(P,S)O4]8(OH)6·28H2O | triclinic | P1 | a = 9.28, b = 11.98, c = 13.25, α = 91.3, β = 75.6, γ = 67.67°, Z = 4 | 1308 | [5] | |||
| Woodhouseite | CaAl3(PO4)(SO4)(OH)6 | trigonal | R3m | a = 6.993, c = 16.386 | 693.95 | 3.0 | Uniaxial (+) nω = 1.636 nε = 1.647 Birefringence: δ = 0.011 | [6] | |
| Ardéalite | Ca2H(PO4)(SO4)•4H2O | monoclinic | a = 5.721, b = 30.95, c = 6.265, β= 117.26° Z = 4 | 986.11 | 2.32 | [7] | |||
| Destinezite Diadochite | Fe2(PO4)(SO4)(OH)•6H2O | triclinic | P1 | a = 9.570, b = 9.716, c = 7.313, α = 98.74°, β = 107.90°, γ = 63.86° Z = 2 | [8] | ||||
| bohuslavite | FeIII4(PO4)3(SO4)(OH)(H2O)10·nH2O (5 ≤ n ≤ 14) | triclinic | P1 | a = 13.376 b = 13.338 c = 10.863 α = 92.80, β = 91.03, γ = 119.92°, Z = 2 | 1675.7 | pink | [9] | ||
| Borickyite | (Ca,Mg)(Fe3+,Al)4(PO4,SO4,CO3)(OH)8·3–7.5H2O | [10] | |||||||
| Camaronesite | [Fe3+(H2O)2(PO3OH)]2(SO4)·1–2H2O | trigonal | R32 | a = 9.0833, c = 42.944, Z = 9 | 3068.5 | [11] | |||
| Fe3+4(PO4)3(SO4)(OH)·18H2O | triclinic | P1 | a=13.376, b 13.338, c 10.863, α 92.80, β 91.03, γ 119.92° | 1675.7 | [12] | ||||
| vanderheydenite | Zn6(PO4)2(SO4)(OH)4·7H2O | monoclinic | P21/n | a = 6.204 b = 19.619, c = 7.782, β = 90.67° | 947.1 | biaxial (–) α = 1.565, β = 1.580 γ = 1.582. 2V = 39.8° | [13] | ||
| Svanbergite | SrAl3(PO4)(SO4)(OH)6 | trigonal | R3m | a = 6.97, c = 16.59 Z=3 | 697.98 | 3.2 | Uniaxial (+) nω = 1.631 - 1.635 nε = 1.646 - 1.649 Birefringence: δ = 0.015 | [14] | |
| Birchite | Cd2Cu2(PO4)2(SO4) ·5H2O | a = 10.489 b = 20.901 c = 6.155 Z=4 | 1349.6 | 3.647 | biaxial positive,
nα = 1.624, nβ = 1.636, nγ = 1.669, 2Vcalc = +63°. |
[15] | |||
| Corkite | PbFe3(OH)6SO4PO4 | trigonal | R3m | a = 7.32, c = 17.02 Z=3 | 781.2 | 4.295 | Uniaxial (-) nω = 1.930 nε = 1.930 n = 1.93 - 1.96 Birefringence 0.03 | [16] | |
| BaAl3(PO4)(SO4)(OH)6 | trigonal | R3m | a = , c = Z=3 | [17] | |||||
| hinsdalite | (Pb,Sr)Al3(PO4)(SO4)(OH)6 | [18] | |||||||
| Tsumebite | Pb2Cu(PO4,SO4)(OH) | [19] | |||||||
| Delvauxite | CaFe43+(PO4,SO4)2(OH)8·4–6H2O | [20] | |||||||
| Rossiantonite | Al3(PO4)(SO4)2(OH)2(H2O)10·4H2O | triclinic | P1 | a = 10.3410, b = 10.9600, c = 11.1446, α = 86.985, β = 65.727, γ = 75.064°, Z = 2 | 1110.5 | [21] | |||
| Schlossmacherite | (H3O,Ca)Al3(AsO4,PO4,SO4)2(OH)6 | [22] | |||||||
| Arthurite | Cu(Fe3+)2(AsO4,PO4,SO4)2(O,OH)2·4(H2O) | [23] | |||||||
| cobaltarthurite | [23] | ||||||||
| Phosphoinnelite | Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3 | triclinic | P1? | a = 5.38, b = 7.10, c = 14.76; α = 99.00°, β = 94.94°, γ = 90.14° Z = 1 | 555 | 3.82 | biaxial (+), α = 1.730, β = 1.745, and γ = 1.764, 2V 90° | [24] | |
| Francolite | (Ca, Mg, Sr, Na)10(PO4, SO4, CO3)6F2–3 | [25] | |||||||
| Al4(UO2)2(PO4)4(SO4)(OH)2 · 18H2O | [26] | ||||||||
| Al4(UO2)2(PO4)4(SO4)(OH)2 · 20H2O | [26] | ||||||||
| Coconinoite | Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2O | monoclinic | C2/c | a =12.45, b = 12.96, c = 17.22, β = 105.7° | [26] | ||||
| xiangjiangite | Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 22H2O | tetragonal | a = 7.17 Å, b = 7.17 Å, c = 22.22 Å Z=1 | 1,142 | Biaxial (-) nα = 1.558 nβ = 1.576 nγ = 1.593 2V: 87° | [27] |
Artificial
| chem | mw | crystal system | space group | unit cell Å | volume | density | comment | references |
|---|---|---|---|---|---|---|---|---|
| [H4N+]2·HSO4−·H2PO4− | [28][29] | |||||||
| NH4(HSO4)0.45(H2PO4)0.55 | orthorhombic | [30] | ||||||
| 18-crown[6]·[NH4][H2PO4]0.5[HSO4]0.5·H2O | orthrhombic | F2dd | a=8.710 b= 28.868 c=31.206 Z=16 | 7846 | 1.346 | dehydrate at 70° | [31] | |
| [(C2H5)4N+]2·HSO4−·H2PO4− | Monoclinic | C2/c | a = 28.0787 b = 11.8671 c = 14.1533 β = 100.739° Z=8 | 4633.46 | 1.303 | colourless; decompose at 353K | [32] | |
| (NH2CH2COOH)3(H2SO4)0.7(H3PO4)0.3 | monoclinic | called TGSP; colourless; ferroelectric, curie point 51 °C; pyroelectric | ||||||
| Na(HSO4)(H3PO4) | monoclinic | P 21 | a = 5.449, b = 6.832, c = 8.718, β = 95.88°, Z = 2 | 322.8 | [33] | |||
| K2(HSO4)(H2PO4) | monoclinic | P 21/c | a = 11.150, b = 7.371, c = 9.436, β = 92.29°, Z = 4 | 774.9 | [33] | |||
| K4(HSO4)3(H2PO4) | triclinic | P 1 | a = 7.217, b = 7.521, c = 7.574, α = 71.52°, β = 88.28°, γ = 86.20°, Z = 1 | 389.1 | [33] | |||
| K4(PO2F2)2(S2O7) | 534.46 | monoclinic | C2/c | a = 13.00, b = 7.543, c = 19.01, β = 130.07°, Z = 4 | 1426.5 | 2.489 | colourless; pyrosulfate + difluorophosphate | [34] |
| K3[O3SOPO2OSO3] | [35] | |||||||
| H1−xTi2(PO4)3−x(SO4)x (x=0.5–1) | [36] | |||||||
| Na2MgTi(SO4)(PO4)2 | trigonal | R3c | a=8.4796 c=21.8091 Z=6 | 1358.1 | 2.818 | [37] | ||
| K2MgTi(SO4)(PO4)2 | cubic | P213 | a=9.8743 Z=4 | 962.84 | 2.872 | [37] | ||
| Ca10-xNax(PO4)6-x(SO4)xF2 | monoclinic | [38] | ||||||
| NaFe2(PO4)(SO4)2 | hexagonal | R3c | a=8.4243 c=21.973 | [39] | ||||
| NaFe1.4V0.6(PO4)(SO4)2 | [40] | |||||||
| [Ni(C14H10N4)3]4(PO4)2(SO4) (C14H10N4=2,2'-bi-1H-benzimidazole) | 3331.96 | cubic | I43d | a = 24.964 Z=4 | 15558 | 1.423 | green | [41] |
| Rb2(HSO4)(H2PO4) | monoclinic | P21/n | a=7.448, b=7.552, c=7.632, β=100.47°, Z=2 | 422.1 | [42][43] | |||
| Rb2(HSO4)(H2PO4) | monoclinic | P21/c | a=11.555, b=7.536, c=9.593, β=91.56, Z=4 | 853.0 | at 160K | [43] | ||
| Rb4(HSO4)3(H2PO4) | orthorhombic | P21212 | a=7.612, b=14.795, c=7.446, Z=2 | 838.6 | [42][43] | |||
| 18-crown[6]·Rb[H2PO4]0.5[HSO4]0.5·3H2O | monoclinic | C2/c | a=19.802 b=8.447 c=25.777 β=101.00° Z=8 | 4232 | 1.572 | dehydrate at 70° | [31] | |
| Rb2MgTi(SO4)(PO4)2 | [37] | |||||||
| Sr4(PO4)2SO4 | [44] | |||||||
| NaZrMg(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
| NaZrCo(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
| NaZrNi(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
| NaZrCu(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
| NaZrZn(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
| NaZrAl(PO4)2(SO4) | hexagonal | R3c | [45] | |||||
| NaZrFe(PO4)2(SO4) | hexagonal | R3c | [45] | |||||
| H3OSb2(SO4)2(PO4) | triclinic | P1 | a=5.134 b=7.908 c=12.855, α=81.401° β=87.253° γ=86.49° | [46] | ||||
| KSb2(SO4)2(PO4) | triclinic | P1 | a=5.1453 =7.9149 c=12.6146, α=82.054° β=87.715° γ=86.655° | [46] | ||||
| RbSb2(SO4)2(PO4) | triclinic | P1 | a=5.1531 b=7.957 c=12.845, α=81.801° β=87.676° γ=86.703° | [46] | ||||
| Cs2(HSO4)(H2PO4) | cubic | ao=4.926 | >105 °C but can be supercooled | [47] | ||||
| Cs2(HSO4)(H2PO4) | monoclinic | P21/n | a = 7.856 b = 7.732 c = 7.827, β= 99.92° Z=2 | 468.3 | 3.261 | can substitute 2.3% ammonium; proton conductivity at 110 °C is 3×10−3 Ω−1cm−1 | [48][49] | |
| Cs3(HSO4)2(H2PO4) | monoclinic | C2/c | a=19.824 b=7.859 c=19.047 β=100.20° Z=4 | 1387.2 | 3.302 | stable against water solution 298-313K; phase transition at 411K | [50] | |
| Cs4(HSO4)3(H2PO4) | monoclinic | C2/c | a=19.945 b=7.8565 c=8.9949 β=100.119° Z=3 | 1387.5 | 3.301 | colourless | [51][52] | |
| Cs5(HSO4)2(H2PO4)3 | cubic | I43d | a=14.5668 | over 381K goes to tetragonal a=4.965 c=5.016 | [53] | |||
| Cs6H(HSO4)3(H2PO4)4 | cubic | I43d | a=14.4758 | 3033.38 | 3.236 | colourless | [54] | |
| Cs5(HSO4)3(H2PO4)2 | monoclinic | C2/c | a=34.07 Å,b=7.661,c=9.158,β=90.44° | 2390 | 3.198 | [55] | ||
| 18-crown[6]·Cs[H2PO4]0.5[HSO4]0.5·3H2O | monoclinic | C2/c | a=19.840 b=8.460 c=26.19 β=101.14 Z=8 | 4313 | 1.689 | dehydrate at 70° | [31] | |
| CsNH4(HSO4)(H2PO4) | [56] | |||||||
| Cs3NH4(HSO4)3(H2PO4) | [56] | |||||||
| Cs2MgTi(SO4)(PO4)2 | [37] | |||||||
| Ba4(PO4)2SO4 | [44] | |||||||
| NaBa6Zr(PO4)5SO4 | cubic | I43d | a = 10.5449 Z=4 | 1172.54 | eulytite mineral structure | [44] | ||
| Ba2Sr2(PO4)2SO4 | [44] | |||||||
| Ba3Sr(PO4)2SO4 | [44] | |||||||
| Ce2O(HPO4)2(SO4). 4H2O | CeIV | [57] | ||||||
| Ce2O(HPO4)2.4(SO4)0.6. 2H2O | CeIII | [58] | ||||||
| [enH2]0.5[CeIII(PO4)(HSO4)(OH2)] | monoclinic | P21/a | a=12.999 b=7.150 c=9.212 β=95.33 | cream colour | [59] | |||
| KSr2Eu(PO4)2SO4 | [44] | |||||||
| RbSr2Eu(PO4)2SO4 | [44] | |||||||
| CsSr2Eu(PO4)2SO4 | [44] | |||||||
| [enH2]0.5[Ho(HPO4)(SO4)(H2O)] | monoclinic | P21/a | a = 12.938 b = 6.834 c = 9.100 β = 88.12° | [60] | ||||
| Pb2Mg2(PO4)2SO4 | [44] | |||||||
| MgPb3(PO4)2(SO4) | cubic | I43d | a = 10.299 Z=4 | 1092.4 | 5.67 | [61] | ||
| CaPb3(PO4)2(SO4) | cubic | I43d | a = 10.296 Z=4 | 1091.5 | 5.77 | [61] | ||
| MnPb3(PO4)2(SO4) | cubic | I43d | a = 10.258 Z=4 | 1079.4 | 5.92 | [61] | ||
| CoPb3(PO4)2(SO4) | cubic | I43d | a = 10.356 Z=4 | 1110.6 | 5.78 | [61] | ||
| NiPb3(PO4)2(SO4) | cubic | I43d | a = 10.434 Z=4 | 1135.9 | 5.65 | [61] | ||
| CuPb3(PO4)2(SO4) | cubic | I43d | a = 10.422 Z=4 | 1132.0 | 5.70 | [61] | ||
| ZnPb3(PO4)2(SO4) | cubic | I43d | a = 10.449 Z=4 | 1140.8 | 5.67 | [61] | ||
| CdPb3(PO4)2(SO4) | cubic | I43d | a = 10.315 Z=4 | 1097.5 | 6.17 | [61] | ||
| SrPb3(PO4)2(SO4) | cubic | I43d | a = 10.369 Z=4 | 1114.8 | 5.93 | [61] | ||
| Th2(PO4)2SO4·2 H2O | decompose 450 °C | [62] |
Organic derivatives
A catenated sulfophosphate has the sulfur and phosphorus joined by an oxygen atom. In biochemistry, metabolism of sulfate may use such a group, for example with adenosine-5'-phosphosulfate.[63]
References
- ↑ Frost, Ray L.; Palmer, Sara J. (September 2011). "A vibrational spectroscopic study of the mixed anion mineral sanjuanite Al2(PO4)(SO4)(OH)·9H2O" (PDF). Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 79 (5): 1210–1214. Bibcode:2011AcSpA..79.1210F. doi:10.1016/j.saa.2011.04.044. PMID 21646042.
- ↑ Beukes, Gerhard J.; Schoch, Aylva E.; Van der Westhuizen, Willem A.; Bok, Louis D. C.; Bruiyn, Hendrik (1984-10-01). "Hotsonite, a new hydrated aluminum-phosphate-sulphate from Pofadder, South Africa". American Mineralogist. 69 (9–10): 979–983. ISSN 0003-004X.
- ↑ Yakubovich, O. V.; Steele, I. M.; Chernyshev, V. V.; Zayakina, N. V.; Gamyanin, G. N.; Karimova, O. V. (August 2014). "The crystal structure of arangasite, Al 2 F(PO 4 )(SO 4 )·9H 2 O determined using low-temperature synchrotron data". Mineralogical Magazine. 78 (4): 889–903. Bibcode:2014MinM...78..889Y. doi:10.1180/minmag.2014.078.4.09. ISSN 0026-461X. S2CID 94078023.
- ↑ Pilkington, E. S.; Segnit, E. R.; Watts, J. A. (December 1982). "Peisleyite, a new sodium aluminium sulphate phosphate". Mineralogical Magazine. 46 (341): 449–452. Bibcode:1982MinM...46..449P. doi:10.1180/minmag.1982.046.341.07. ISSN 0026-461X. S2CID 129726668.
- ↑ Mills, S. J.; Ma, C.; Birch, W. D. (December 2011). "A contribution to understanding the complex nature of peisleyite". Mineralogical Magazine. 75 (6): 2733–2737. Bibcode:2011MinM...75.2733M. doi:10.1180/minmag.2011.075.6.2733. ISSN 0026-461X. S2CID 18661193.
- ↑ "Woodhouseite". www.mindat.org. Retrieved 2022-05-25.
- ↑ BALENZANO, F; DELL'ANNA, L.; DI PIERRO, M.; FIORE, S. (1982). "Ardealite, Ca2H(PO4) (SO4).4H2O, un rarissimo fosfato-solfato idrato di calcio: risultati mineralogici preliminari". Ardealite, Ca2H(PO4) (SO4).4H2O, Un Rarissimo Fosfato-solfato Idrato di Calcio: Risultati Mineralogici Preliminari. 38 (2): 899–900. ISSN 0037-8828.
- ↑ Peacor, Donald R. (1999). "Destinezite ("Diadochite"), Fe2(PO4)(SO4)(OH)·6H2O: Its Crystal Structure and Role as a Soil Mineral at Alum Cave Bluff, Tennessee†". Clays and Clay Minerals. 47 (1): 1–11. Bibcode:1999CCM....47....1P. doi:10.1346/CCMN.1999.0470101. ISSN 0009-8604. S2CID 98406559.
- ↑ Mauro, Daniela; Biagioni, Cristian; Bonaccorsi, Elena; Hålenius, Ulf; Pasero, Marco; Skogby, Henrik; Zaccarini, Federica; Sejkora, Jiří; Plášil, Jakub; Kampf, Anthony R.; Filip, Jan (2019-12-20). "Bohuslavite, Fe 4 3 + (PO4)3(SO4)(OH)(H2O)10·nH2O, a new hydrated iron phosphate-sulfate". European Journal of Mineralogy. 31 (5–6): 1033–1046. Bibcode:2019EJMin..31.1033M. doi:10.1127/ejm/2019/0031-2892. ISSN 0935-1221. S2CID 213555293.
- ↑ Frost, Ray L.; Palmer, Sara J.; Xi, Yunfei (June 2012). "Is the mineral borickyite (Ca,Mg)(Fe3+,Al)4(PO4,SO4,CO3)(OH)8·3–7.5H2O the same as delvauxite CaFe43+(PO4,SO4)2(OH)8·4–6H2O?". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 92: 377–381. Bibcode:2012AcSpA..92..377F. doi:10.1016/j.saa.2012.02.102. PMID 22446787.
- ↑ Kampf, A. R.; Mills, S. J.; Nash, B. P.; Housley, R. M.; Rossman, G. R.; Dini, M. (June 2013). "Camaronesite, [Fe 3+ (H 2 O) 2 (PO 3 OH)] 2 (SO 4 )·1–2H 2 O, a new phosphate-sulfate from the Camarones Valley, Chile, structurally related to taranakite". Mineralogical Magazine. 77 (4): 453–465. Bibcode:2013MinM...77..453K. doi:10.1180/minmag.2013.077.4.05. ISSN 0026-461X. S2CID 129777006.
- ↑ Mauro, D.; Biagioni, C.; Bonaccorsi, E.; Pasero, M.; Skogby, H.; Zaccarini, F. (2018). "A new iron (III) phosphate-sulfate from Apuan Alps (Tuscany, Italy): a difficult puzzle solved through a multi-technique approach". Congresso Sgi-Simp 2018: 521.
- ↑ Elliott, Peter; Kolitsch, Uwe (2018-10-31). "Description and crystal structure of vanderheydenite, Zn6(PO4)2(SO4)(OH)4·7H2O, a new mineral from Broken Hill, New South Wales, Australia". European Journal of Mineralogy. 30 (4): 835–840. Bibcode:2018EJMin..30..835E. doi:10.1127/ejm/2018/0030-2750. ISSN 0935-1221. S2CID 134655965.
- ↑ "Svanbergite". www.mindat.org. Retrieved 2022-05-25.
- ↑ Elliott, P.; Brugger, J.; Pring, A.; Cole, M. L.; Willis, A. C.; Kolitsch, U. (2008-05-01). "Birchite, a new mineral from Broken Hill, New South Wales, Australia: Description and structure refinement". American Mineralogist. 93 (5–6): 910–917. Bibcode:2008AmMin..93..910E. doi:10.2138/am.2008.2732. ISSN 0003-004X. S2CID 95773593.
- ↑ "Corkite". www.mindat.org. Retrieved 2022-05-25.
- ↑ Izbrodin, Ivan A.; Ripp, German S.; Doroshkevich, Anna G. (January 2011). "Aluminium phosphate and phosphate-sulphate minerals in kyanite schists of the Ichetuyskoye area, West Transbaikalia, Russia: crystal chemistry and evolution". Mineralogy and Petrology. 101 (1–2): 81–96. Bibcode:2011MinPe.101...81I. doi:10.1007/s00710-010-0135-5. ISSN 0930-0708. S2CID 129698260.
- ↑ Frost, Ray L.; Palmer, Sara J.; Xi, Yunfei (August 2011). "A vibrational spectroscopic study of the mineral hinsdalite (Pb,Sr)Al3(PO4)(SO4)(OH)6". Journal of Molecular Structure. 1001 (1–3): 43–48. Bibcode:2011JMoSt1001...43F. doi:10.1016/j.molstruc.2011.06.014.
- ↑ Frost, Ray L.; Palmer, Sara J. (September 2011). "Vibrational spectroscopic study of the mineral tsumebite Pb2Cu(PO4,SO4)(OH)". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 79 (5): 1794–1797. Bibcode:2011AcSpA..79.1794F. doi:10.1016/j.saa.2011.05.058. PMID 21680232.
- ↑ Frost, Ray L.; Palmer, Sara J. (April 2011). "A Raman and infrared spectroscopic study of the mineral delvauxite CaFe43+(PO4,SO4)2(OH)8·4–6H2O—A 'colloidal' mineral". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 78 (4): 1250–1254. Bibcode:2011AcSpA..78.1250F. doi:10.1016/j.saa.2010.12.039. PMID 21277823.
- ↑ Galli, E.; Brigatti, M. F.; Malferrari, D.; Sauro, F.; De Waele, J. (2013-10-01). "Rossiantonite, Al3(PO4)(SO4)2(OH)2(H2O)10{middle dot}4H2O, a new hydrated aluminum phosphate-sulfate mineral from Chimanta massif, Venezuela: Description and crystal structure". American Mineralogist. 98 (10): 1906–1913. doi:10.2138/am.2013.4393. hdl:11585/185099. ISSN 0003-004X. S2CID 102265894.
- ↑ Frost, Ray L.; Palmer, Sara J.; Xi, Yunfei (February 2012). "Raman spectroscopy of the multi-anion mineral schlossmacherite (H3O,Ca)Al3(AsO4,PO4,SO4)2(OH)6". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 87: 209–213. Bibcode:2012AcSpA..87..209F. doi:10.1016/j.saa.2011.11.040. PMID 22169025.
- 1 2 Palmer, Sara J.; Frost, Ray L. (May 2011). "The structure of the mineral arthurite (AsO4,PO4,SO4)2(O,OH)2·4H2O – A Raman spectroscopic study". Journal of Molecular Structure. 994 (1–3): 283–288. doi:10.1016/j.molstruc.2011.03.034.
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- ↑ Mieritz, Daniel; Davidowski, Stephen K.; Seo, Dong-Kyun (October 2016). "Accessing alkali-free NASICON-type compounds through mixed oxoanion sol–gel chemistry: Hydrogen titanium phosphate sulfate, H1−Ti2(PO4)3−(SO4) (x=0.5–1)". Journal of Solid State Chemistry. 242: 116–125. Bibcode:2016JSSCh.242..116M. doi:10.1016/j.jssc.2016.02.007.
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- ↑ Chisholm, Calum R. I.; Haile, Sossina M. (1999-12-01). "Structure and thermal behavior of the new superprotonic conductor Cs 2 (HSO 4 )(H 2 PO 4 )". Acta Crystallographica Section B: Structural Science. 55 (6): 937–946. Bibcode:1999AcCrB..55..937C. doi:10.1107/S0108768199009921. ISSN 0108-7681. PMID 10927436.
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- ↑ Makarova, Irina; Grebenev, Vadim; Dmitricheva, Elena; Vasiliev, Ilya; Komornikov, Vladimir; Dolbinina, Valentina; Mikheykin, Alexey (2016-02-01). "M m H n ( X O 4 ) ( m + n )/2 crystals: structure, phase transitions, hydrogen bonds, conductivity. II. Structure and properties of Cs 3 (HSO 4 ) 2 (H 2 PO 4 ) and Cs 4 (HSO 4 ) 3 (H 2 PO 4 ) single crystals". Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials. 72 (1): 133–141. doi:10.1107/S2052520615023069. ISSN 2052-5206. PMID 26830805.
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- ↑ Makarova, I. P.; Grebenev, V. V.; Komornikov, V. A.; Selezneva, E. V. (November 2016). "New crystals of the CsHSO4–CsH2PO4–H2O system". Crystallography Reports. 61 (6): 918–922. Bibcode:2016CryRp..61..918M. doi:10.1134/S1063774516060079. ISSN 1063-7745. S2CID 99983650.
- ↑ Haile, Sossina M.; Calkins, Pamela M. (November 1998). "X-Ray Diffraction Study of Cs5(HSO4)3(H2PO4)2, a New Solid Acid with a Unique Hydrogen-Bond Network". Journal of Solid State Chemistry. 140 (2): 251–265. Bibcode:1998JSSCh.140..251H. doi:10.1006/jssc.1998.7884.
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{{cite journal}}: Missing or empty|title=(help) - ↑ Brandel, Vladimir; Dacheux, Nicolas; Rousselle, Jérôme; Genet, Michel (August 2002). "Synthesis of some new thorium phosphates". Comptes Rendus Chimie. 5 (8–9): 599–606. doi:10.1016/S1631-0748(02)01419-4.
- ↑ PubChem. "Adenosine-5'-phosphosulfate". pubchem.ncbi.nlm.nih.gov. Retrieved 2022-07-14.
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