アジ化リチウム

アジ化ナトリウムと硝酸リチウムとの複分解により得られる。

${\displaystyle {\ce {NaN3\ + LiNO3 -> LiN3\ + NaNO3}}}$

アジ化ナトリウムと硫酸リチウムとの反応でも得られる^[2]。

${\displaystyle {\ce {2NaN3\ + Li2SO4 -> 2 LiN3\ + Na2SO4}}}$

1. ↑ Pringle, G. E.; Noakes, D. E. (February 1968). “The crystal structures of lithium, sodium and strontium azides”. Acta Cryst. B24 (2): 262-269. doi:10.1107/S0567740868002062. 
2. ↑ http://www.lambdasyn.org/synfiles/lithiumazid.htm

• Hofman-Bang, Niels; Bjerrum, Jannik; Gloor, U.; Magnéli, Arne; Magnéli, Arne; Pestmalis, Herbert; Åsbrink, Stig (1957). “Preparation of Lithium Azide”. Acta Chemica Scandinavica 11: 581. doi:10.3891/acta.chem.scand.11-0581. 
• Younk, Edward H.; Kunz, A. Barry (1997). “An ab initio investigation of the electronic structure of lithium azide (LiN₃), sodium azide (NaN₃), and lead azide [Pb(N₃)₂]”. International Journal of Quantum Chemistry 63: 615. doi:10.1002/(SICI)1097-461X(1997)63:3<615::AID-QUA2>3.0.CO;2-Z. 
• Gordienko, A.B.; Poplavnoi, A.S. (1997). “The Application of ab-initio Linear Combination of Pseudo-Atomic-Orbital Scheme for the Electronic Structure of Lithium Azide LiN₃”. Physica status solidi (b) 202: 941. doi:10.1002/1521-3951(199708)202:2<941::AID-PSSB941>3.0.CO;2-K. 
• Zhu, W; Xiao, J; Xiao, H (2006). “Density functional theory study of the structural and optical properties of lithium azide”. Chemical Physics Letters 422: 117. doi:10.1016/j.cplett.2006.02.017.