Borate iodide
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Mixed anion compounds
The borate iodides are mixed anion compounds that contain both borate and iodide anions. They are in the borate halide family of compounds which also includes borate fluorides, borate chlorides, and borate bromides.
| name | chem | mw | crystal system | space group | unit cell Å | volume | density | comment | references |
|---|---|---|---|---|---|---|---|---|---|
| Cr3B7O13I | F4c | a = 12.171 Z=8 | 18029 | 4.17 | [1] | ||||
| Mn3B7O13I | F43c | a = 12.32 Z=8 | 1870 | 4.09 | [1] | ||||
| Fe3B7O13I | Pca21 | a = 8.654, c = 12.2336 Z=4 | 915.57 | 4.19 | [1] | ||||
| Co3B7O13I | F43c | a = 12.119 Z=8 | 1779.9 | 4.38 | [1] | ||||
| Ni3B7O13I | Pca21 | a = 08.511 c = 12.037 Z=4 | 871.9 | 4.47 | magnetoelectric, ferroelectric and ferroelastic | [1] | |||
| Cu3B7O13I | F43c | a = 12.0203 Z=8 | 1736.8 | 4.60 | [1] | ||||
| Ag4B4O7I2 | 840.52 | hexagonal | P6122 | a=8.9576 c=45.1956 Z=12 | 3140.6 | 5.33 | [2] | ||
| tin iodide borate | Sn3[B3O7]I | orthorhombic | Pbca | a = 10.718, b = 8.523, and c = 20.168 Z = 8 | [3] | ||||
| La[B5O8(OH)(H2O)2I] | 495.86 | monoclinic | P21/n | a=6.529 b=15.494 c=10.744 β=90.353 Z=4 | 1086.8 | 3.03 | colourless | [4] | |
| La[B7O11(OH)(H2O)3I] | 581.48 | orthorhombic | P21/n | a=8.178 b=17.251 c=9.849 Z=4 | 1389.4 | 2.78 | colourless | [5] | |
| Ce[B5O8(OH)(H2O)2I] | 497.07 | monoclinic | P21/n | a= 6.498 b=15.416 c=10.704 β=90.306 Z=4 | 1072.3 | 3.079 | colourless | [4] | |
| Ce[B7O11(OH)(H2O)3I] | 582.69 | orthorhombic | P21/n | a=8.1641 b=17.205 c=9.816 Z=4 | 1378.8 | 2.807 | colourless | [5] | |
| Pr[B5O8(OH)(H2O)2I] | 497.86 | monoclinic | P21/n | a= 6.488 b=15.392 c=10.686 β=90.254 Z=4 | 1067.0 | 3.099 | green | [4] | |
| Pr[B7O11(OH)(H2O)3I] | 583.48 | orthorhombic | P21/n | a=8.1504 b=17.205 c=9.814 Z=4 | 1376.2 | 2.816 | light green | [5] | |
| Nd[B5O8(OH)(H2O)2I] | 501.19 | monoclinic | P21/n | a=6.4763 b=15.350 c=10.6734 β=90.316 Z=4 | 1061.0 | 3.137 | purple | [4] | |
| Nd[B7O11(OH)(H2O)3I] | 586.81 | orthorhombic | P21/n | a=8.1464 b=17.199 c=9.735 Z=4 | 1372.2 | 2.841 | purple | [5] | |
| Sm[B7O11(OH)(H2O)3I] | 592.92 | orthorhombic | P21/n | a=8.102 b=17.158 c=9.733 Z=4 | 1352.9 | 2.911 | colourless | [5] | |
| dilead borate iodide | Pb2BO3I | trigonal | P321 | NLO 10 × KDP | [6] | ||||
| Pb2B5O9I | 739.35 | orthorhombic | Pnm2 | a=11.561 b=11.700 c=6.524 Z=4 | 882.5 | 5.565 | colourless or yellow | [7] | |
| Pb6O4(BO3)I | 1492.85 | orthorhombic | Pmmn | a= 5.78 b=9.72 c=10.63 Z=2 | 597 | 8.302 | colourless | [8] | |
| Pb10O4(BO3)3I3 | 2693.03 | monoclinic | Cc | a=16.6423 b=9.0277 c=16.9746 β=115.658 Z=4 | 2298.8 | 7.781 | colourless | [9] | |
| tetrabismuth borate tetraoxy iodide | Bi4BO7I | 1085.6 | orthorhombic | Immm | a=3.959 b=13.453 c=3.969 Z=1 | 211.4 | 8.5279 | dark orange | [10] |
| Pu[B7O11(OH)(H2O)2I] | 668.57 | monoclinic | P21/n | a=8.110 b=17.060 c=9.792 β=90.133 Z=4 | 1354.9 | 3.278 | pale blue | [4] | |
References
- 1 2 3 4 5 6 Schnelle, Walter; Schmid, Hans (2015-05-20). "Magnetic and structural phase transitions of multiferroic boracites M3B7O13X (M = 3 d transition metal Cr–Zn or Mg; X = halogen Cl, Br, I)". Physical Review B. 91 (18) 184411. Bibcode:2015PhRvB..91r4411S. doi:10.1103/PhysRevB.91.184411. ISSN 1098-0121.
- ↑ Volkov, Sergey N.; Charkin, Dmitri O.; Arsent'ev, Maxim Yu.; Povolotskiy, Alexey V.; Stefanovich, Sergey Yu.; Ugolkov, Valery L.; Krzhizhanovskaya, Maria G.; Shilovskikh, Vladimir V.; Bubnova, Rimma S. (2020-03-02). "Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag4B4O7X2 (X = Br, I) Borate Halides". Inorganic Chemistry. 59 (5): 2655–2658. doi:10.1021/acs.inorgchem.0c00306. ISSN 0020-1669. PMID 32049501. S2CID 211101969.
- ↑ Schönegger, Sandra; Pielnhofer, Florian; Saxer, Andreas; Wurst, Klaus; Huppertz, Hubert (2019-05-06). "Synthesis and Characterization of the Tin Iodide Borate Sn3[B3O7]I". Inorganic Chemistry. 58 (9): 6088–6094. doi:10.1021/acs.inorgchem.9b00377. ISSN 0020-1669. PMID 30964677. S2CID 106408547.
- 1 2 3 4 5 Polinski, Matthew J.; Wang, Shuao; Cross, Justin N.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2012-07-16). "Effects of Large Halides on the Structures of Lanthanide(III) and Plutonium(III) Borates". Inorganic Chemistry. 51 (14): 7859–7866. doi:10.1021/ic3009317. ISSN 0020-1669. PMID 22734798.
- 1 2 3 4 5 Polinski, Matthew J.; Alekseev, Evgeny V.; Darling, Victoria R.; Cross, Justin N.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2013-02-18). "A New Family of Lanthanide Borate Halides with Unusual Coordination and a New Neodymium-Containing Cationic Framework". Inorganic Chemistry. 52 (4): 1965–1975. doi:10.1021/ic302309z. ISSN 0020-1669. PMID 23360290.
- ↑ Yu, Hongwei; Koocher, Nathan Z.; Rondinelli, James M.; Halasyamani, P. Shiv (2018-05-22). "Pb2BO3I: A Borate Iodide with the Largest Second-Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials". Angewandte Chemie International Edition. 57 (21): 6100–6103. doi:10.1002/anie.201802079. PMID 29512313.
- ↑ Huang, Yi-Zhi; Wu, Li-Ming; Wu, Xin-Tao; Li, Long-Hua; Chen, Ling; Zhang, Yong-Fan (2010-09-22). "Pb2B5O9I: An Iodide Borate with Strong Second Harmonic Generation". Journal of the American Chemical Society. 132 (37): 12788–12789. Bibcode:2010JAChS.13212788H. doi:10.1021/ja106066k. ISSN 0002-7863. PMID 20738133.
- ↑ Li, Kuan; Yalikun, Alimujiang; Su, Zhi (2020). "[O2Pb3]2 (BO3)I: a new lead borate iodide with 1∞[O2Pb3] double chains". Dalton Transactions. 49 (26): 8985–8990. doi:10.1039/D0DT01722A. ISSN 1477-9226. PMID 32558837. S2CID 219924590.
- ↑ Zhou, Jinjie; Wu, Hongping; Yu, Hongwei; Hu, Zhanggui; Wu, Yicheng (2019). "Pb10O4(BO3)3I3: a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method". Dalton Transactions. 48 (40): 14996–15001. doi:10.1039/C9DT02579K. ISSN 1477-9226. PMID 31369009. S2CID 199055810.
- ↑ Volkov, Sergey; Bubnova, Rimma; Krzhizhanovskaya, Maria; Galafutnik, Lydia (2020-12-01). "The first bismuth borate oxyiodide, Bi4BO7I: commensurate or incommensurate?". Acta Crystallographica Section B. 76 (6): 992–1000. Bibcode:2020AcCrB..76..992V. doi:10.1107/S2052520620012640. ISSN 2052-5206. PMID 33289711. S2CID 227947646.
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Salts and covalent derivatives of the iodide ion | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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