Europium(III) iodide

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Europium(III) iodide[1]
Names
IUPAC name
Europium(III) iodide
Other names
Europium triiodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.941 Edit this at Wikidata
EC Number
  • 244-721-0
  • InChI=1S/Eu.3HI/h;3*1H/q+3;;;/p-3
    Key: OEGMUYNEEQNVBV-UHFFFAOYSA-K
  • [I-].[I-].[I-].[Eu+3]
Properties
EuI
3
Molar mass 532.677 g mol−1
Appearance colourless crystals[2]
Melting point decomposes[1]
Structure[1][3][4]
BiI3
octahedral
Related compounds
Other anions
EuF3, EuCl3, EuBr3
Other cations
SmI3, GdI3
Related compounds
EuI2
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Europium(III) iodide is an inorganic compound, a salt containing europium and iodine with the chemical formula EuI3.[1]

Europium metal reacts directly with iodine to form europium(III) iodide:[5]

2 Eu + 3 I2 → 2 EuI3

Hydrated europium(III) iodide can be prepared dissolving europium(III) oxide or europium(III) carbonate in hydroiodic acid:[1][6]

Eu2O3 + 6 HI + 6 H2O → 2 EuI3·9H2O

Europium powder reacts with iodine in THF to form a THF adduct of europium(III) iodide:[7][8]

2 Eu + 3 I2 + 7 THF → [EuI2(THF)5][EuI4(THF)2]

The adduct can be formulated more simply as EuI3(THF)3.5.

Structure

Reactivity

References

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