Potassium hexafluoroarsenate

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Potassium hexafluoroarsenate
Names
IUPAC name
potassium hexafluoro-λ⁵-arsanuide
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.037.351 Edit this at Wikidata
EC Number
  • 241-102-7
KEGG
UNII
  • InChI=1S/AsF6.K/c2-1(3,4,5,6)7;/q-1;+1
    Key: DITNVAZRXJOPSJ-UHFFFAOYSA-N
  • F[As-](F)(F)(F)(F)F.[K+]
Properties
AsF6K
Molar mass 228.0103 g·mol−1
Appearance white powder
Melting point 400 °C (752 °F; 673 K)
Hazards
GHS labelling:[1]
GHS06: ToxicGHS09: Environmental hazard
Danger
H301, H331, H410
P261, P264, P270, P271, P273, P301+P316, P304+P340, P316, P321, P330, P391, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Potassium hexafluoroarsenate is an inorganic chemical compound with the chemical formula KAsF6.[2][3]

Potassium hexafluoroarsenate can be prepared by direct action of arsenic pentafluoride and potassium fluoride:

AsF5 + KF → KAsF6

Also, it can be synthesized by the action of hydrofluoric acid on arsenic pentafluoride in the presence of potassium perbromate:[4]

KBrO4 + 3HF + 2AsF5 + KF → KAsF6 + AsF6[H3O]

Also, potassium hexafluoroarsenate is synthesized by treating arsenic pentachloride and potassium chloride in the presence of hydrofluoric acid:

AsCl5 + KCl + 6HF → KAsF6 + 6HCl

Physical characteristics

Safety

References

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